Effect of HRT and Internal Recycle Ratio on Removal of Organic and Nitrogen in Swine Wastewater by Anoxic-Oxic Process Combined with Membrane

분리막이 결합된 무산소·호기 공정을 이용한 축산폐수처리에서 수리학적체류시간 및 내부반송율이 유기물 및 질소제거에 미치는 영향

  • Whang, gye dae (Department of environmental science and engineering in Kyunghee University) ;
  • Lee, bong hee (Department of environmental science and engineering in Kyunghee University) ;
  • Lee, hyun duk (Kumho Engineering)
  • 황규대 (경희대학교 환경 응용화학대학 수처리 공정연구실) ;
  • 이봉희 (경희대학교 환경 응용화학대학 수처리 공정연구실) ;
  • 이현덕 ((주)금호엔지니어링)
  • Received : 2004.08.18
  • Accepted : 2004.10.05
  • Published : 2004.11.30

Abstract

The objective of this study was to determine the optimal operation conditions in an anoxic oxic process to eliminate both organic and nitrogen matters in swine wastewater. For the purpose of this, the removal efficiency was evaluated with various HRTs and internal recycling ratio. During the whole 580 days of experiment, HRTs had been gradually decreased in an order of 20, 14, 12 and l0days, and the internal recycle ratio was kept at 20Q. So as to determine the effect of the internal recycle ratio on the nitrogen removal, the internal recycle ratio had been gradually increased from 20Q to 50Q while HRT was maintained at 12days. As a result, it was shown that the removal efficiency of organic matter was above 95% regardless of changing of HRTs. The average influent concentration of TCODcr and SCODcr were 24,854 mg/L and 18,920 mg/L, respectively. Average removal efficiency of TKN was shown to be nearly 98% when HRT was kept at 12days; however, the $NH_4{^+}-N$ concentration of effluent was shown to be increased when the loading rate of $NH_4{^+}-N$ was increased to $0.602 kgNH_4{^+}-N/m^3$-day by means of decreasing HRT to 10days. It was concluded that nitrogen loading rates should be more considered rather than organic loading rates in case of determining an optimal HRT. When gradually increasing the internal recycle ratio from 20Q to 50Q, the removal efficiency of organic matters and TKN were 96% and 98%, respectively so that no significant changes in removal efficiency was detected. However, when the internal recycle ratio was kept at 50Q, it was revealed that the $NO_3-N$ concentration of effluent seemed to drop and the average $NO_3-N$ concentration of effluent was around 52 mg/L.

Keywords

References

  1. 김도연, 침지형 분리막과 철의 전기분해가 결합된 무산소 . 호 기공정을 이용한 고농도 양돈폐수 처리, 경희대학교 석사학위논문 (2001)
  2. 김상근, 혐기성 여상과 장기포기조를 이용한 매립지 침출수중 암모니아성 질소 제거, 인하대학교 석사학위논문, (1997)
  3. 박성균, 박현수 외, MLE 공정을 이용한 양돈폐수의 질소 제거 특성, 대한상하수도학회지, 14, pp. 147-156, (2000)
  4. 황규대, 김민호, 조철휘, 돈사폐수 처리를 위한 활성슬러지 공정에서 동역학적 계수에 관한 연구, 대한환경공학회지, 14, pp. 529-537 (1998)
  5. 황규대, 조철휘, 정민모, 무산소 . 호기공정을 이용한 축산폐수 처리에서 유입수 C/N비와 내부반송률이 질소 제거에 미치는 영향, 대한환경공학회지, 21, pp. 2205-2220 (1999)
  6. Abeling, C. F. and Seyfried., Anaerobic-aerobic treatment of high strength ammonium wastewater nitrogen removal via nitrate, Water Sci. Tec., 26, pp. 1007-1015 (1992)
  7. Fatos Germirli, Fate of residuals in nitrification-denitrification treatment of piggery wastewaters, Bioresource Technology, 45, Issue 3, pp. 205-211 (1993)
  8. Ivan, M., Alenka, P. and France, M., Nitrification/Denitrification in nitrogen high-strength liquid wastes, Water Res., 30, pp. 2107-2111 (1996)
  9. Knoblock, M. D., Sutton, P. M., Mishra, P. N., Gupa, K. and Janson, A., Membrane biological reactor system for treatment of oily wastewater, Water Environ. Res., 66, pp. 133-139 (1994)
  10. Kurbiel, J., Metabolism of suspended matter in activated sludge treatment, 4th international confer on water pollution research, prague, September (1968)
  11. U.S. EPA, Nitrogen control, EPA/625/R-93/010 (1993)