DOI QR코드

DOI QR Code

Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings (III);Film Properties of Model Composite Latex

라텍스 입자구조가 필름형성 및 필름물성에 미치는 영향 (III);모델 복합라텍스 입자의 필름물성

  • Ju, In-Ho (Department of Chemical Engineering, Myongji University) ;
  • Byeon, Ja-Hun (Department of Chemical Engineering, Myongji University) ;
  • Wu, Jong-Pyo (Department of Chemical Engineering, Myongji University)
  • 주인호 (명지대학교 공과대학 화학공학과) ;
  • 변자훈 (명지대학교 공과대학 화학공학과) ;
  • 우종표 (명지대학교 공과대학 화학공학과)
  • Published : 2004.09.30

Abstract

Film properties of monodispersed model composite latexes with particle size of 190 nm, which consist of n-butyl acrylate as a soft phase monomer and methyl methacrylate as a hard phase monomer with different morphology was examined. Five different types of model latexes were used in this study such as random copolymer particle, soft-core/hard-shell particle, hard-core/soft-shell particle, gradient type particle, and mixed type particle. Tensile strength and tensile elongation at break of final films were evaluated. Those properties can be interpreted in terms of PBA/PMMA phase ratio and their morphology. The interfacial adhesion strength was also evaluated using $180^{\circ}$ peel strength measurement and cross hatch cutting test.

Keywords

References

  1. J. M. Asua (ed.), 'Polymeric Dispersions : Principles and Applications', p. 397, Kluwer Academic Pub., Dordrecht (1997)
  2. Y. C. Chen, V. L. Dimonie, and M. S. El-Aasser, Effect of Interfacial Phenomena on the Development of Particle Morphology in a Polymer Latex Systems, Macromolecules, 24, 3779 (1991) https://doi.org/10.1021/ma00013a007
  3. S. Lee and A. Rudin, Practical Methods to Control Mophology of Heterogeneous Polymer Particles, Makromol. Chem., Rapid Commun., 92, 53 (1995)
  4. D. I. Lee and T. Ishikawa, The Formation of Inverted Core-Shell Latexes, J. Polym. Sci., Polym. Chem. Ed., 21, 147, (1983) https://doi.org/10.1002/pol.1983.170210115
  5. Y. C. Chen, V. L. Diamonie, O. L.Shaffer, and M. S. El-Aasser, Development of Morphology in Latex Particles, Polymer International, 30, 185 (1993) https://doi.org/10.1002/pi.4990300208
  6. M. R. Grancio and D. J. Williams, The Mophology of the Monomer-Polymer Particle in Styrene-Emulsion Polymerization, J. Polym. Sci., Polym. Chem., 8, 2617 (1970) https://doi.org/10.1002/pol.1970.150080927
  7. C. Dimonie, M. S. El-Aasser, and A. Klein, Core-Shell Emulsion Copolymerization of Styrene and Acrylonitrile on Polystyrene Seed Particles, J. Polyme. Sci., Polym. Chem. Ed., 22, 2197 (1984) https://doi.org/10.1002/pol.1984.170220921
  8. I. Cho and K. W. Lee, Morphology of Latex Particles Formed by Po1y(methyl methacrylate)-Seeded Emulsion Polymerization of Styrene, J. Appl. Polym. Sci., 30, 1903 (1985) https://doi.org/10.1002/app.1985.070300510
  9. D. I. Lee and T. Ishikawa, The Formation of Inverted Core-Shell Latexes, J. Polyme. Sci., Polym. Chem. Ed., 21, 147 (1983) https://doi.org/10.1002/pol.1983.170210115
  10. D. R. Stutman, A. Klein, M. S. El-Aasser, and J. W. Vanderhoff, Mechanism of Core/Shell Emulsion Polymerization, Ind. Engr. Chem. Prod. Res. Dev., 24, 404 (1985) https://doi.org/10.1021/i300019a014
  11. T. R. Paxton, Particle Morphology in Artificial Compostie polymer Latex Systems, J. Coll. Inter. Sci., 31, 19 (1969) https://doi.org/10.1016/0021-9797(69)90077-0
  12. T. Matsumoto and M. Okubo, Control of Particle Morphology in Emulsion Polymerization, Makromol. Chem. Macromol. Symp., 35/36, 307 (1990) https://doi.org/10.1002/masy.19900350119
  13. J. W. Vanderhoff, H. L. Tarkowski, M. C. Jenkius, and E. B. Bradford, Formation of Films from Polymer Dispersion, J. Macromol. Chem., 1, 131 (1966)
  14. O, Fickian, M. A, Winnik, and M, D, Croucher, Fluorescence Strudies of Coalescence and Film Formation Dispersion Particles, Macromolecules, 23, 2673 (1990) https://doi.org/10.1021/ma00212a013
  15. S. Croll, Drying Behavior of Acrylic Latexes, J. Coat. Technol., 58, 41 (1986)
  16. D. J. Meier and F. Lin, Theoretical Aspects of Film Formation, Polym. Mater. Sci. Eng., 73, 83 (1995)
  17. M. S. El-Aasser, A Study of Latex Film Formation by Atomic Force Microscopy. 2. Film Formation vs Rhelological Properties: Theory and Experiment, Langmuir, 12, 2774 (1996) https://doi.org/10.1021/la951554w
  18. R. E. Dillon, L, A, Matheson, and E. B. Bradford, The Transport of Water Through Latex Films, J. Colloid Sci., 6, 108 (1951) https://doi.org/10.1016/0095-8522(51)90031-1
  19. I. H. Ju, J. W. Ahn, J. H. Byun, and J. P. Wu, Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings (I): Preparation and Characterization of Model Composite Latex, J. of The Korean Oil Chemists' Society, 21(1), 69 (2004)
  20. I. H. Ju and J. P. Wu, Effect of Latex Particle Morphology on the Film Formation and Film Properties of Acrylic Coatings (II): Film Forming Behavior of Model Composite Latex, J. of The Korean Oil Chemists' Society, 21(2), 132 (2004)