Korean Journal of Materials Research (한국재료학회지)

Materials Research Society of Korea (한국재료학회)
권호 표지
DOI QR코드

DOI QR Code

Synthesis of Iron Oxide Using Ferrous Sulfate by Ozone Treatment

황산제일철 용액의 오존 처리에 의한 산화철 합성

  • Published : 2004.05.01
Download PDF
⟨ Previous Next ⟩

Abstract

The influences of the ozone oxidation, reaction temperature and NaOH equivalent ratio on the iron oxide formation were studied with fixed ferrous sulfate concentration(0.5M $FeSO_4$ㆍ$7H_2$O). Geothite($\alpha$-FeOOH) and/or Magnetite ($Fe_3$$O_4$) were synthesized depending on the reaction conditions. The characteristics of the synthesized powders were evaluated by XRD, SEM and quantitative phase analysis. The synthetic conditions to get Goethite were quite different from the results of Kiyama's and the Goethite was conveniently synthesized at low temperature and at low NaOH equivalent ratio.

Keywords

References

  1. Y. Tamura, G. S. Chyo and I. Katsura, Water Res., 13, 21 (1979) https://doi.org/10.1016/0043-1354(79)90250-1
  2. J.-H. Oh, S.-H. Lee, N.-K. Kang and M. Kim, J. Kor. Inst. Met. & Mater., 31(10), 1345 (1993)
  3. T.-B. Byun, J.-Y. Lee, T.-H. Kim, J.-G. Son and S.-W. Kweon, J. Kor. Inst. Met. & Mater., 30(8), 911 (1992)
  4. K. Matsumoto, T. Akiraka, K. Hukai and S. Nakatani, Japan Patent Koukai, 56-17290 (1981)
  5. S. Okamoto and I. Konkasura, Magnetic Ceramics, Shihoudou, Tokyo, (1985)
  6. J.-H. Oh, Prog. Chem. & Chem. Indus., 24(11), 722 (1984)
  7. A. A. V. D. Giessen, J. Phys. Chem. Solid, Pergamon Press, 28, 343 (1967) https://doi.org/10.1016/0022-3697(67)90130-8
  8. 'Advanced Technology of the Utilization of Ozon (New Edition)', Sansyuyobou
  9. M. Kiyama, Bull. Chem. Soc. Japan, 47, 1646 (1974) https://doi.org/10.1246/bcsj.47.1646