Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Chemical Reaction of Carbon Dioxide with AMP in w/o Emulsion Membrane

W/O 에멀션액막에서 이산화탄소와 AMP의 화학반응

  • 박상욱 (부산대학교 응용화학공학부) ;
  • 최병식 (부산대학교 응용화학공학부) ;
  • 김성수 (부산카톨릭대학교 환경과학부) ;
  • 이재욱 (서강대학교 화학공학과)
  • Published : 2004.12.01
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Abstract

Carbon dioxide was absorbed into water-in-oil (w/o) emulsion composed of aqueous 2-amino-2-methyl-1-propanol (AMP) droplets as a dispersed phase and benzene solutions of polybutene and polyisobutylene as a continuous phase in a flat-stirred vessel to investigate the effect of non-Newtonian rheological behavior on the rate of chemical absorption of $CO_2$, where the reaction between $CO_2$ and AMP in the aqueous phase was assumed to be a pseudo-first-order reaction. It was expressed that PIB with elastic property made the rate of chemical absorption of $CO_2$ accelerated by comparison of mass transfer coefficient of $CO_2$ in the non-Newtonian liquid with that in the Newtonian liquid.

본 연구에서는 준 회분식 교반조를 사용하여 polybutene (PB)와 polyisobutylene (PIB)고분자를 용해한 벤젠 용액을 연속상, 물을 불연속상으로 구성한 w/o 에멀션액막에 $CO_2$을 흡수시켜 흡수속도를 측정하였다. 점탄성을 나타내는 Deborah 수를 사용하여 점탄성 비뉴튼액체에서 구한 부피물질전달계수 ($k_La$)를 고찰하고, 수용액에 첨가한 2-amino-2-methyl-1-propanol(AMP)와 $CO_2$의 반응 메카니즘을 해석하였다.

Keywords

References

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