Korean Membrane Journal

한국막학회 (The Membrane Society of Korea)
권호 표지

Fabrication of High Permeable Nanoporous Carbon-SiO$_2$ Membranes Derived from Siloxane-containing Polyimides

  • Kim, Youn Kook (National Research Laboratory for Membranes, School of Chemical Engineering, College of Engineering, Hanyang University) ;
  • Han, Sang Hoon (National Research Laboratory for Membranes, School of Chemical Engineering, College of Engineering, Hanyang University) ;
  • Park, Ho Bum (National Research Laboratory for Membranes, School of Chemical Engineering, College of Engineering, Hanyang University) ;
  • Lee, Young Moo (National Research Laboratory for Membranes, School of Chemical Engineering, College of Engineering, Hanyang University)
  • 발행 : 2004.12.01
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초록

The silica containing carbon (C-SiO$_2$) membranes were fabricated using poly(imide siloxane) (PIS) having -CO- swivel group. The characteristics of porous C-SiO$_2$ structures prepared by the pyrolysis of poly(imide siloxane) were related with the micro-phase separation between the imide block and the siloxane block. Furthermore, the nitrogen adsorption isotherms of the CMS and the C-SiO$_2$ membranes were investigated to define the characteristics of porous structures. The C-SiO$_2$ membranes derived from PIS showed the type IV isotherm and possessed the hysteresis loop, which was associated with the mesoporous carbon structures, while the CMS membranes derived from PI showed the type I isotherm. For the molecular sieving probe, the C-SiO$_2$ membranes pyrolyzed at 550, 600, and 700$^{\circ}C$ showed the O$_2$ permeability of 924, 1076, and 367 Barrer (1 ${\times}$ 10$\^$-10/㎤(STP)cm/$\textrm{cm}^2$$.$s$.$cmHg) and O$_2$/N$_2$ selectivity of 9, 8, and 12.

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