Macromolecular Research

  • 제12권5호
  • /
  • Pages.451-458
  • /
  • 2004
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Characterization and Rheological Properties of Dilute-solutions of Three Different Families of Water-soluble Copolymers Prepared by Solution Polymerization

  • 발행 : 2004.10.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Water-soluble polyacrylamides hydrophobically modified with small amounts of N,N-dialkylacrylamides [N,N-dihexylacrylamide (DHAM) and N,N-dioctylacrylamide (DOAM)] have been prepared through free radical solution polymerizations using two hydrophobic initiators derived from 4,4' -azobis(4-cyanopentanoic acid) (ACVA) and long linear chains consisting of 12 and 16 carbon atoms (C12 and C16). This procedure resulted in polyacrylamides containing hydrophobic groups along the chain as well as at the chain ends. We compare the properties of this class of polymers, termed "combined associative polymers", with those of the multisticker (with hydrophobic groups along the polymer chain) and telechelic (with hydrophobic groups at the chain ends) associative polymers. These materials were prepared using DHAM or DOAM and a hydrophobic initiator (ACVA) modified with alkyl chains of two different lengths. Polymers having molecular weights (M$\_$w/) of ca. 175,000 and hydrophobic contents [H] of ca. 0.8 mol% were prepared using 0.07 mol% of initiator relative to the total monomer feed. We investigated the effects that the type, localization, and concentration of the hydrophobic groups have on the viscosities of the associative polymer solutions.

키워드

참고문헌

  1. Water-soluble polymers, in Encyclopedia of polymer Science and Engineering v.17 C. L. McCormick;J. Bock;D. N. Schulz
  2. Polymeric Materials Encyclopedia v.11 K. C. Tam;C. Tiu;J. C. Salamone(ed.)
  3. Chemistry and Technology of Water-Soluble Polymers J. C. Finch
  4. Polymer v.24 W. Brostow https://doi.org/10.1016/0032-3861(83)90119-2
  5. Macromolecules v.25 S. A. Ezzell;C. L. McCormick https://doi.org/10.1021/ma00033a007
  6. Polym. Int. v.50 B. Grassl;J. Francois;L. Billon https://doi.org/10.1002/pi.751
  7. Langmuir v.13 R. Jenkins;D. Bassett;D. Wolf;O. Nuyken https://doi.org/10.1021/la960612q
  8. Polymer v.39 E. Volpert;J. Selb;F. Candau https://doi.org/10.1016/S0032-3861(97)00393-5
  9. Macromolecules v.32 E. Jimenez-Regalado;J. Selb;F. Candau https://doi.org/10.1021/ma990999e
  10. Macromolecules v.33 E. Jimenez-Regalado;J. Selb;F. Candau https://doi.org/10.1021/ma000579l
  11. Macromolecules v.29 R. May;J. P. Kaczmarski;J. E. Glass https://doi.org/10.1021/ma9507655
  12. Polymer v.33 C. Maechlings-Strasser;F. Clouet;J. Francois https://doi.org/10.1016/0032-3861(92)90018-R
  13. Polymer v.33 C. Maechlings-Strasser;J. Francois;F. Clouet;C. Tripette https://doi.org/10.1016/0032-3861(92)90742-F
  14. Macromolecules v.34 S. X. Ma;S. L. Cooper https://doi.org/10.1021/ma001772i
  15. Polymer v.29 C. L. McCormick;T. Nonaka;C. B. Johnson https://doi.org/10.1016/0032-3861(88)90092-4
  16. Macromolecules v.26 A. Hill;F. Candau;J. Selb https://doi.org/10.1021/ma00069a017
  17. Macromolecules v.32 Q. T. Pham;W. B. Russel;J .C. Thibeaut;W. Lau https://doi.org/10.1021/ma990215x
  18. Macromolecules v.35 C. Tsitisilianis;I. IIiopoulos https://doi.org/10.1021/ma011391k
  19. Macromolecules v.35 A. N. Semenov;M. Rubinstein https://doi.org/10.1021/ma0117965
  20. Polymer v.42 W. K. Ng;K. C. Tam;R. D. Jenkins https://doi.org/10.1016/S0032-3861(00)00280-9
  21. Macromolecules v.30 E. E. Kathmann;L. A. White;C. L. McCormick https://doi.org/10.1021/ma961214x
  22. Langmuir v.16 E. Jimenez-Regalado;J. Selb;F. Candau https://doi.org/10.1021/la000168y
  23. Macromolecules v.33 S. Nilsson;K. Thuresson;B. Lindman;B. Nystrom https://doi.org/10.1021/ma001203a
  24. Polym. Mater. Sci. Eng. v.57 P. L. Valint Jr.;J. Bock;D. N. Schulz
  25. Macromolecules v.18 T. A. Witten Jr.;M. H. Cohen https://doi.org/10.1021/ma00152a019
  26. Langmuir v.13 B. Xu;L. Li;A. Yekta;Z. Masoumi;S. Kanagalingam;M. A. Winnik;K. Zhang;P. M. Macdonald https://doi.org/10.1021/la960799l
  27. Macromolecules v.34 G. L. Smith;C. L. McCormick https://doi.org/10.1021/ma001554p
  28. Macromolecules v.28 B. Rao;Y. Uemura;L. Dyke;P. M. Mcdonald https://doi.org/10.1021/ma00106a018
  29. Macromolecules v.31 K. C. Tam;R. D. Jenkins;M. A. Winnik;D. R. Bassett https://doi.org/10.1021/ma980148r
  30. Macromolecules v.29 E. Alami;M. Almgren;W. Brown;J. Francois https://doi.org/10.1021/ma951174h