한국섬유공학회지 (Textile Science and Engineering)

  • 제41권5호
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  • Pages.358-364
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  • 2004
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  • 1225-1089(pISSN)
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  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지

플러렌 변성 폴리스티렌의 물성에 관한 연구

Studies on the Physical Properties of Fullerene-Modified Polystyrenes

  • 이석 (단국대학교 고분자공학과, 기능성 고분자 신소재 연구센터) ;
  • 김환기 (단국대학교 고분자공학과, 기능성 고분자 신소재 연구센터) ;
  • 김건형 (서울대학교 재료공학부) ;
  • 김정안 (한국과학기술연구원 고분자하이브리드 센터) ;
  • 강호종 (단국대학교 고분자공학과, 기능성 고분자 신소재 연구센터)
  • 발행 : 2004.10.01
⟨ 이전 논문 다음 논문 ⟩

초록

Star-shaped polystyrenes with the [60]fullerene core were synthesised via anionic polymerization. The solution, thermal, and UV absorbance properties were investigated as a function of number of branched polystyrene chains on the [60]fullerene core. The solution viscosity (intrinsic viscosity) of the [60]fullerene-modified polystyrene decreased with the number of branching due to molecular entanglement. The better coating property of the [60]fullerene-modified polystyrene compared with those of the polystyrene/[60]fullerene mixtures seems to arise from a lower aggregation state of the [60]fullerene core induced by the branched polystyrene chain. An increase in the glass transition temperature of the modified polystyrene with the number of branched chains was observed as well.

키워드

참고문헌

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