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전분 충전 아크릴레이트 필름의 α-Amylase에 의한 생분해

Biodegradation of Starch-Filled Acrylate Film by α-Amylase

  • 김정두 (부경대학교 응용화학공학부) ;
  • 유수용 (부경대학교 응용화학공학부) ;
  • 감상규 (제주대학교 토목환경공학부) ;
  • 주창식 (부경대학교 응용화학공학부) ;
  • 이민규 (부경대학교 응용화학공학부)
  • 발행 : 2004.09.01

초록

The biodegradability of vinyl acetate acrylate resin and com starch blend was studied by determination of the reduced sugars produced after enzymatic hydrolysis. The starch hydrolysis reaction by $\alpha-amylase$ was achieved within 5 minutes. Optimal ranges of temperature and pH for the starch hydrolysis by $\alpha-amylase$ were around $80^{\circ}C$ and 6.5-7.2, respectively. The biodegradability of the starch-filled acrylate films increased as the content of starch increased. The biodegradation of starch in the starch-filled acrylate film by $\alpha-amylase$ was about 48.6% of that of pure starch. This value of biodegradable starch-filled acrylate film gave a good result with enzymatic shortcut test. The surface morphologies of the starch-filled acrylate film after enzymatic hydrolysis were investigated by scanning electron microscopy (SEM).

키워드

참고문헌

  1. Polymer(Korea) v.24 no.1 Mechanical properties and biodegradability of PCL/TPS blends Shin, C. H.;Y. J. Kim;B. S. Kim;B. Y. Shin
  2. Nature v.270 Hydrolysis of polyesters by lipases Tokiwa, Y.;T. Suzuki https://doi.org/10.1038/270076a0
  3. Polym. Mater. Sci. Eng. v.76 Synthesis and properties of new biodegradable polyesters derived from diacids and diglycidyl ethers Mang, M.;J. White;S. Kram;D. Rick;R. Bailey;P. Swanson
  4. J. Environ. Polym. Degrad. v.6 Biodegradation of an epoxy-based thermoplastic polyester, poly(-hydroxy ester ether) in a laboratory-scale compost system Rick, D. L.;J. W. Davis;S. L. Kram;M. N. Mang;T. D. Lickly https://doi.org/10.1023/A:1021817413415
  5. J. Appl. Polym. Sci. v.26 Hydrolysis of copoleysters containing aromatic and aliphatic ester blocks by lipase Tokiwa, Y.;T. Suzuki https://doi.org/10.1002/app.1981.070260206
  6. Enzyme Microb. Technol. v.20 Enzymatic degradation of an aliphatic polycarbonate, poly (tetramethyene carbonate) Suyama, T.;Y. Tokiwa https://doi.org/10.1016/S0141-0229(96)00084-1
  7. J. of Kor. Ind. & Eng. Chem. v.5 no.6 Study on the biodegradable aliphatic polyester (V) Park, T. W.;H. J. Kang;Y. J. Kim;C. G. Lee
  8. Adv. Polym. Sci. v.157 Aliphatic polyesters: abiotic and biotic degradation and degradation products Hakkarainen, M. https://doi.org/10.1007/3-540-45734-8_4
  9. Tappi Journal v.73 Degradable polyethylene film Gage, P.
  10. Advances in Chemistry Series v.134 Biodegradable fillers in thermoplastic Grifin, G. J. L. https://doi.org/10.1021/ba-1974-0134.ch016
  11. Starch Chemistry and Technology(2nd ed.) Otey, F. H.;W. M. Doane;Whistler, P. L.(ed.);Bemiller, J. N.(ed.);Paschall, E. F.(ed.)
  12. Polymer Sci. and Technol. v.5 no.1 Characteristics of starch-filled biodegradable plastics Kim, Y. O.;W. Y. Jo;D. M. Jo
  13. Polymer Degradation and Stability v.84 no.1 Thermal degradation of cellulose derivatives/starch blends and sisal fibre biocomposites Alvarez, V. A.;A. Vazquez https://doi.org/10.1016/j.polymdegradstab.2003.09.003
  14. European Polymer Journal v.37 no.5 Structure-property relation in low-density polyethylene-starch immiscible blends Raj, B.; V .Annadurai;R. Somasheker;M. Raj;S. Siddaramaiah https://doi.org/10.1016/S0014-3057(00)00193-2
  15. European Polymer Journal v.37 no.3 Properties of injection moulded blends of starch and modified biodegradable polyesters Mani, M.;M. Bhattacharya https://doi.org/10.1016/S0014-3057(00)00155-5
  16. Polymer Degradation and Stability v.60 Structure and properties of degradable polyolefin-starch blends Zuchowska, D.;R. Steller;W. Meissner https://doi.org/10.1016/S0141-3910(97)00110-9
  17. J. Environ. Polym. Degrad. v.1 Starch, plastic materials preparation, physical properties, and biodegradability(a review of recent USDA research) Swanson, C. L.;R. L. Shogren;G. F. Fanta;S. H. Imam https://doi.org/10.1007/BF01418208
  18. J. Appl. Polym. Sci. v.52 Properties of blends of starch and synthetic polymers containing anhydride groups Vaidya, U. R.;M. Bhattacharya https://doi.org/10.1002/app.1994.070520505
  19. J. Appl. Polym. Sci. v.74 Thermoplastic starch/PVAI compounds: preperation, processing, and properties Liu, Z.;Y. Feng;X. S. Yi https://doi.org/10.1002/(SICI)1097-4628(19991209)74:11<2667::AID-APP14>3.0.CO;2-D
  20. Polymer v.40 Processing, performance and biodegradability of a thermoplastic aliphatic polyester/starch system Ratto, J. A.;P. J. Stenhouse;M. Auerbach;J. Mitchell;R. Farrell https://doi.org/10.1016/S0032-3861(99)00014-2
  21. J. Appl. Polym. Sci. v.76 Blends of thermoplastic starch and polyesteramide: processing and properties Averous, L.;N. Fauconnier;L. Moro;C. Fringant https://doi.org/10.1002/(SICI)1097-4628(20000516)76:7<1117::AID-APP16>3.0.CO;2-W
  22. U.S. Patent, 4,016,117 Biodegradable synthetic resin sheet material containing starch and a fatty material Griffin, G. J. L.
  23. U.S. Patent, 4,021,388 Synthetic resin sheet material Griffin, G. J. L.
  24. Starch/Strake v.42 Roper, H.;H. Koch https://doi.org/10.1002/star.19900420402
  25. Polymer Degradation and Stability v.47 Environmentally degradable starch filled low density polyethylene Shan, P. B.;S. Bandopadhyay;J. B. Bellare https://doi.org/10.1016/0141-3910(94)00088-P
  26. J. of Appl. Polym. Sci. v.79 Structure and properties of casing films blended with starch and waterborne polyurethane Wu, Q.;L. Zhang https://doi.org/10.1002/1097-4628(20010314)79:11<2006::AID-APP1009>3.0.CO;2-F
  27. J. of Kor. Ind. & Eng. Chemistry v.3 no.3 Biodegradable polyolefin composites containing starches Lim, D. L.;S. S. Im
  28. Polymer(Korea) v.22 no.2 Biodegradable blends of PCL and starch graft derivatives Kim, S. H.;I. J. Chin;J. S. Yoon;K. H. Lee;M. N. Kim;J. S. Jung
  29. J. Appl. Polym. Sci. v.22 A new biodegradable plastic made from starch graft poly (methyl acrylate) copolymer Dennerbrg, R. J.;R. J. Bothast;T. P. Abbott https://doi.org/10.1002/app.1978.070220214
  30. Anal. Chem. v.3 Use of dinitrosalicyclic acid reagent for determination of reducing sugar Miller, L. G.
  31. Kor. J. Biotechnol. Bioeng. v.11 no.1 Measurement for determining the biodegradation of starch polyethylene film by ${\alpha}$-amylase Choi, S. H.;K. N. Kang;T. H. Park;P. K. Shin

피인용 문헌

  1. Mechanical Properties of Crosslinked Starch-Filled Waterborne Acrylate Film and Biodegradation by α-Amylase vol.14, pp.3, 2005, https://doi.org/10.5322/JES.2005.14.3.359