Macromolecular Research

  • 제12권4호
  • /
  • Pages.427-430
  • /
  • 2004
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Synthesis and Binding Properties of a Calix[4]crown-6-functionalized Polymeric Ion Acceptor

  • 발행 : 2004.08.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Calix[4]crown-6-2,4-bis(2-hydroxyethyl ether) (2), which has crown-6 moieties at the 1- and 3-positions and hydroxyethyl functions at the 2- and 4-positions, was prepared for the syntheses of polyester 3 and polyurethane 4 by reactions with adipoyl chloride and hexamethylene diisocyanate, respectively. The ion binding characteristics of monomer 2 and polymers 3 and 4 toward alkali and alkali earth metal ions were measured by liquid-liquid extraction from the aqueous phase into the organic phase. We observed that the polyurethane 4 has a higher binding affinity toward various metal cations when compared to polyester 3, which exhibits cesium ion selectivity.

키워드

참고문헌

  1. Calixarenes: A Versatile Class of Macrocyclic Compounds J. Vicens;V. Bohmer
  2. J. Inc. Phe. Mac. Chem. v.37 J. S. Kim;W. K. Lee;W. B. Sim;J. W. Ko;M. H. Cho;D. Y. Ra;J. W. Kim https://doi.org/10.1023/A:1008149218391
  3. J. Chem. Soc., Perkin Trans. v.1 J. S. Kim;O. J. Shon;W. B. Sim;S. K. Kim;M. H. Cho;J. G. Kim; I. H. Suh;D. W. Kim
  4. Bull. Korean Chem. Soc. v.22 J. S. Kim;P. Thuery;M. Nierlich;J. A. Rim;S. H. Yang;J. K. Lee;K. H. Cho;J. H. Lee;J. Vicens https://doi.org/10.1007/BF02701504
  5. Tetrahedron Lett. v.39 N. Reynier;J. F. Dozol;M. Saadioui;Z. Asfari;J. Vicens https://doi.org/10.1016/S0040-4039(98)00678-9
  6. Syn. Met. v.90 F. A. Neu;M. J. S. Weill https://doi.org/10.1016/S0379-6779(98)80001-5
  7. Tetrahedron Lett. v.43 M. Mathieu;Z. Asfari;J. Vicens https://doi.org/10.1016/S0040-4039(01)02399-1
  8. J. Tetrahedron Lett. v.40 Z. Asfari;P. Thuery;M. Nierlich;J. Vicens https://doi.org/10.1016/S0040-4039(98)02421-6
  9. Tetrahedron Lett. v.61 V. Bohmer;R. Dorrenbacher;M. Frings;M. Heydenreich;D. Paoli;W. Vogt;G. Ferguson;I. Thondorf
  10. Anal. Chim. Acta v.371 C. P. Jimenes;L. Escriche;J. Casabo https://doi.org/10.1016/S0003-2670(98)00325-0
  11. J. Polym. Sci.: Polym. Chem. v.32 H. Deligoz;M. Yilmaz https://doi.org/10.1002/pola.1994.080321518
  12. J. Polym. Sci.: Polym. Chem. v.33 H. Deligoz;M. Yilmaz https://doi.org/10.1002/pola.1995.080331619
  13. J. Polym. Sci.: Polym. Chem. v.37 S. Memon;A. Yilmaz;M. Yilmaz https://doi.org/10.1002/(SICI)1099-0518(19991201)37:23<4351::AID-POLA11>3.0.CO;2-L
  14. J. Polym Sci.: Polym. Lett. v.26 S. Shinkai;H. Kawaguchi;O. Manabe https://doi.org/10.1002/pol.1988.140260903
  15. Macromolecules v.29 D. Gravett;J. E. MGuillet https://doi.org/10.1021/ma950870e
  16. Chem. Lett. K. Ohto;Y. Tanaka;K. Inoue
  17. Talanta v.52 J. S. Kim;S. K. Kim;J. W. Ko https://doi.org/10.1016/S0039-9140(00)00489-6
  18. React. Funct. Polym. v.47 S. Memon;G. Uysal;M. Yilmaz https://doi.org/10.1016/S1381-5148(01)00029-3
  19. React. Funct. Polym. v.50 S. Memon;G. Uysal;M. Yilmaz https://doi.org/10.1016/S1381-5148(01)00099-2
  20. React. Funct. Polym. v.31 H. Deligoz;M. Yilmaz https://doi.org/10.1016/1381-5148(96)00030-2
  21. J. Macromol. Sci.,: Pure and Appl. Chem. v.37 S. Memon;A. Ylmaz;M. Yilmaz https://doi.org/10.1081/MA-100101128
  22. Bull. Korean Chem. Soc. W. H. Seol;S. H. Kim;C. W. Lee;M. S. Gong
  23. Solvent Extr. Ion Exch. H. Deligoz;M. Yilmaz
  24. Talanta v.49 J. S. Kim;M. H. Cho;S. C. Lee;J. H. Pang;J. H. Lee;A. Ohki https://doi.org/10.1016/S0039-9140(98)00362-2
  25. Talanta v.51 J. S. Kim;M. H. Cho;J. H. Cho;R. A. Bartsch;Y. I. Lee;I. H. Kim https://doi.org/10.1016/S0039-9140(99)00253-2