Fibers and Polymers

The Korean Fiber Society (한국섬유공학회)
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Synthesis and Characterization of Sodium Acrylate and 2-Acrylamido-2- Methylpropane Sulphonate (AMPS) Copolymer Gels

  • Published : 2004.06.01
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Abstract

A series of superabsorbents based on acrylic acid (AA), sodium acrylate, 2-acrylamido-2-methylpropane sulphonic acid, N,N'-methylene bis-acrylamide (MBA) were prepared by inverse suspension polymerization. These hydrogels were further crosslinked on the surface with polyethylene glycol-600 (PEG-600). The water absorbency or swelling behaviors for these xerogels in water and 0.9% saline solutions, both under free condition and under load were investigated. Absorption characteristics of these hydrogels were found to depend on nature and concentration of crosslinker in the system. It was also found that the saline absorption was significantly improved as the incorporation of AMPS in the polymer was increased. The surface crosslinking introduced in the polymers was found to improve the absorption under load characteristics without lowering the free water absorption capacities of the polymer to a considerable extent.

Keywords

References

  1. F. L. Buchholz, Chemtech, 2, 38 (1994)
  2. F. L. Buchholz and N. A. Peppas, 'Super Absorbent Polymer', ACS Symposium Series, Washington DC, 573, 121 (1994)
  3. F. L. Buchholz and T. Graham, 'Modem Superabsorbent Polymer Technology', p.152, VCH, 1, Wiley, New York, 1998
  4. S. A. Hashemi, F. Askari, S. Nafisi, and H. Omidian, J. Appl. Polym. Sci., 50,1851 (1993) https://doi.org/10.1002/app.1993.070501022
  5. H. Omidian, S. A. Hashemi, F. Askari, and S. Nafisi, Polymer, 40, 1753 (1999) https://doi.org/10.1016/S0032-3861(98)00394-2
  6. H. Omidian, S. A. Hashemi, F. Askari, and S. Nafisi, J. Appl. Polym. Sci., 54, 241 (1994) https://doi.org/10.1002/app.1994.070540210
  7. T. Gotoh, Y. Nakatani, and S. Sakohara, J. Appl. Polym. Sci., 69, 895 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980801)69:5<895::AID-APP8>3.0.CO;2-H
  8. Q. Yan and A. Hoffman, Polymer, 36, 887(1995) https://doi.org/10.1016/0032-3861(95)93123-4
  9. E. J. Lind, U. S. Patent, 5116719 (1992)
  10. W. F. Lee and R. J. Wu, J. Appl. Polym. Sci., 64, 1701 (1997) https://doi.org/10.1002/(SICI)1097-4628(19970531)64:9<1701::AID-APP5>3.0.CO;2-J
  11. W. F. Lee and R. J. Wu, J. Appl. Polym. Sci., 69, 229 (1998) https://doi.org/10.1002/(SICI)1097-4628(19980711)69:2<229::AID-APP3>3.0.CO;2-P
  12. W. F. Lee and R. J. Wu, J. Appl. Polym. Sci., 72, 1221 (1999) https://doi.org/10.1002/(SICI)1097-4628(19990531)72:9<1221::AID-APP11>3.0.CO;2-C
  13. M. Tominaga, Japan Patent, 6022659 (1994)
  14. J. R. Gross and R. S. Harland, U. S. Patent, 5082723 (1992)
  15. S. A. Goldman, N. A. Haynes, T. L. Mansfied, M. Plischke, H. L. Retzsch, T. Walker, and G. A. Young, WO, 9526209 (1995)
  16. K. Kimura, K. Nagasuna, and T. Namba, Eur. Patent, 349240 (1990)