A Study on the NOx Removal in Multiple Plasma/Catalyst Combined Reactor

플라즈마/촉매 복합 다단 반응기를 이용한 NOx 저감

  • Published : 2004.05.01

Abstract

Plasma/catalyst combined reactor was designed to overcome the limits of plasma and catalyst technologies. Optimum reductant and catalyst was selected from screening test. Experiments about the concentrations of reactant and $H_2O$ and the effect of temperature were carried out. Hydrocarbons with double bond such as propylene and so on were more reactive than any other reductants in plasma/catalyst condition. Photocatalyst, especially hombikat >$TiO_2$ with the largest surface area among the catalysts tested, showed the highest DeNOx efficiency in plasma/catalyst reaction. As the concentration of $H_2O$ increased, the removal of NO was enhanced. The increased concentration of >$O_2$ promoted the reaction of NO which was oxidized to$NO_2$.

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References

  1. Catal. Today v.2 Catalytic Reduction of Nitrogen Oxides-a Review on the Fundamentals and Technology H.Bosch;F.Janssen https://doi.org/10.1016/0920-5861(88)80002-6
  2. Hydrocarbon Processing SCR Process Cuts NOx Emissions H.L.Hill
  3. Catal. Today v.10 Removal of Nitrogen Monoxide from Exhaust Gases through Novel Catalytic Processes M.Iwamoto;H.Hamada https://doi.org/10.1016/0920-5861(91)80074-J
  4. Int. Phys. Conf. Ser.(Electrostatics '87) Removal of NOx by Corona Discharge Induced by Sharp Rising Nanosecond Pulsed Voltage S.Masuda;Y.Wu
  5. IEEE, Trans. IAS v.26 Control of NOx by Positive and negative Pulsed Corona Discharge S.Masuda;H.Nakao
  6. IEEE Trans. IAS v.22 A Method for the Removal of Sulfur Dioxide from Exhaust Gas Utilizing Pulsed Streamers for Electron Energization A.Mizuno;J.S.Clements;R.H.Davis
  7. IEEE Trans. IAS v.25 Industrial Experiments on Pulsed Corona Simultaneous Removal of NOx and SO₂ from Flue Gas by means of Impulse Streamer Corona L.Civitano;G.Dinelli;M.Rea
  8. Catal. Today v.59 Plasmacatalytic Process for Environmental Problems K.P.Francke;H.Miessner;R.Rudolph https://doi.org/10.1016/S0920-5861(00)00306-0
  9. Appl. Catal. B:Environ v.28 Slective Catalytic Reduction of Nitrogen Oxides by Combining a Non-thermal Plasma and a V₂O₃-WO₃/TiO₂catalyst S.Broer;T.Hammer https://doi.org/10.1016/S0926-3373(00)00166-1
  10. Transactions of KSAE A Study of Non-thermal Plasma Generation on a Photocatalytic Reactor Using a Ceramic Honeycomb Monolith Substrate G.S.Son;S.W.Yun;S.H.Ko;D.J.Kim;J.W.Song;k.Y.Lee