Low-stress Mechanical Properties of Poly(ethylene terephthalate) and Poly(trimethylene terephthalate) Knit Fabrics Treated by Helium Atmospheric Pressure Plasma

헬륨 대기압 플라즈마 처리에 의한 PTT 및 PET 경편물의 낮은 응력하에서의 물리적 성질

  • Published : 2004.04.01

Abstract

Poly(trimethylene terephthalate) (PTT) and poly(ethylene terephthalate) (PET) warp knitted fabrics were treated by helium atmospheric pressure glow discharge plasma. Weight loss (%) measurements and scanning electron microscopy (SEM) analysis showed removal of lubricant and contamination by plasma etching effect. X-ray photoelectron spectroscopy (XPS) analysis revealed that surface oxidation resulted in formation of hydrophilic groups which enhanced moisture regain (%), after storage. Plasma treatments caused PTT to have more profound surface oxidation and cleaning effect. It was found that low-stress mechanical properties, evaluated by Kawabata evaluation system (KES-FB), were enhanced by plasma treatment. Surface property changes by plasma etching played important roles in changing not only low-stress mechanical properties but also bulk properties of both fabrics, as a result of changes in interfiber and interyarn friction.

Keywords

References

  1. Chem. Fibers Int. v.46 Corterra Poly(trimethylene terephthalate) - New Polymeric Fiber for Carpet H.Chuah
  2. Sen-I Gakkaish v.56 no.8 Studies on the Molecular Structure and Crystallization Kinetics of Polytrimethylene Terephthalate G.Chen;X.Huang;L.Gu
  3. J. Appl. Polym Sci. v.81 Effect of Zone Drawing on the Structure and Properties of Melt-spun Poly(trimethylene terephthalate) Fiber W.Lyoo;H.Lee;B.Ji;S.Han;K.Koo;S.Kim;J.Kim;J.Lee;T.Son;W.Yoon
  4. J. Polym. Sci. Part B: Polym. Phys. v.40 Intrinsic Birefringence of Poly(trimethylene terephthalate) H.Chuah
  5. Polymer v.20 The Structure of Poly(trimethylene terephthalate) I.Desborough;I.Hall;J.Neisser
  6. J. Polym. Sci. Part B: Polym. Phys. v.24 Conformational Reorganization Viewed by the Raman Spectrum of Aromatic Polyester J.Kim;M.Lewin;B.Bulkin
  7. Chem. Fibers Int. v.45 Mechanical Properties of Fibers Made by Polytrimethylene Terephthalate H.Traub;P.Hirt;H.Herlinger
  8. J. Polym. Sci. Polym. Phys. Ed. v.14 The Mechanical Properties and Structure of Poly(m-methylene terephthalate) Fibers I.Ward;M.Wilding
  9. Melliand Textiber v.76 no.9 Dyeing Properties of Poly(trimethylene terephthalate) Fibers H.Traub;P.Hirt;H.Herlinger
  10. Text. Chem. Color. Am. D. v.1 no.3 Dyeing Behavior of 100% Poly(trimethylene terephthalate) (PTT) Textiles Y.Yang;H.Brown;P.Casey
  11. J. Appl. Polym. Sci. v.86 Some Sorption Characteristics of Poly(trimethylene terephthalate) with Disperse Dyes Y.Yang;H.Brown;S.Li
  12. AATCC Rev. v.2 no.8 Dyeing of PTT/PET Blends Y.Yang;S.Li;H.Brown;P.Casey
  13. Langmuir v.15 Selective Etching of Semicrystalline Polymers: CF₄Gas Plasma Treatment of Poly(ethylene) M.Riekerink;J.Terlingen;G.Engbers;J.Feijen
  14. J, Mater. Sci. v.34 Mechanical Strength of Cold Plasma Treated Fibers D.Ferrante;S.Iannace;T.Montetta
  15. Textile Res. J. v.69 Low Temperature Plasma Treatment of Linen K.Wong;X.Tao;C.Yuen;K.Yeung
  16. Textile Res. J. v.72 no.2 Dimensional and Surface Properties of Plasma and Silicone Treated Wool Fabric M.Kim;T.Kang
  17. Textile Res. J. v.70 no.1 Characterizing Polyester Fabrics Treated in Electrical Discharges of Radio-Frequency Plasma I.Negulescu;S.Despa;J.Chen;B.Collier
  18. J.Mater. Process. Tech. v.123 no.1 Low Temperature Plasma-Treated Nylon Fabrics J.Yip;K.Chan;K.Sin;K.Lan
  19. J. Adhesion Sci. Technol. v.17 no.6 The Effects of Atmospheric Pressure Helium Plasma Treatment on Adhesion and Mechanical Properties of Aramid Fibers Y.Hwang;Y.Qiu;C.Zhang;B.Jarrard;R.Stedeford;J.Tsai;Y.Pakr;M.McCord
  20. Textile Res. J. v.72 no.6 Modifyinf Nylon and Polypropylene Fabrics with Atmospheric Pressure Plasma M.McCord;Y.Hwang;P.Hauser;Y.Qiu;J.Cuomo;O.Hankins;M.Bourham;L.Canup
  21. ISBN 0-7503-0545-2 Industrial Plasma Engineering J.Roth
  22. Thin Solid Film Micromechanical Characterization of Plasma Treated Polymer Surface S.Dahl;D.Rats;J.Stebut;L.Martinu;J.Klemberg-Sapieha
  23. Textile Res. J. v.64 no.10 Objective Hand Measurement of Nonwoven Fabrics(Part I)-Development of the Equation S.Kawabata;M.Niwa;F.Wang
  24. Statisitcal Methods(8th Ed.) G.Snedecor;W.Cochran
  25. 202nd The Electrochemical Societly Meeting Surface Modification of Organic Polymer Films Treated in Atmospheric Plasmas Y.Hwang;S.Matthews;Y.Park;M.McCord;M.Bourham
  26. J. Appl. Polym. Sci. v.79 Cold Plasma Surface Modification of Conventionally and Nonconventionally Plasticized Poly(viny1 chloride)-Based Flexible Films: Global and Specific Migration of Additives into Isooctane J.Audic;F.Poncin-Epailkkard;D.Reyx;J.Brosse
  27. J. Appl. Polym. Sci. Appl. Polym. Symp. v.38 Effects of Glow Discharges on Fibers and Fabrics T.Yasuda;M.Gazicki;H.Yasuda
  28. Textile Res. J. The Effects of Helium Atmospheric Pressure Plasma Treatment on Low-Stress Mechanical Properties of Polypropylene Nonwoven Fabrics Y.Hwang;J.An;M.McCord;B.Kang;S.Park