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침전법을 이용한 YAG분말의 합성 및 소결

Preparation and Sintering of YAG Powder Prepared by Precipitation

  • 발행 : 2004.03.01

초록

Al 및 Y 질산염 용액에 탄산수소암모늄(NH$_4$HCO$_3$)을 침전제로 사용하여 YAG 분말을 합성하였다. 침전물을 attrition-milling한 결과, $Y_2$O$_3$와 YAG 상이 생성되었으며, 분쇄한 침전물을 110$0^{\circ}C$에서 1시간 하소하여 결정상이 잘 발달된 YAG 단일상 분말을 얻을 수 있었다. 분말의 소결성은 소결조제 SiO$_2$(500ppm Si)의 첨가에 관계없이 매우 우수하였다. 모든 시편은 130$0^{\circ}C$에서 이미 70% 이상의 밀도로 소결되었으며,140$0^{\circ}C$에서도 -83%의 밀도를 나타내었다. SiO$_2$로 도핑한 시편은 도핑하지 않은 시편 보다 치밀화가 약간 향상되었으며, 1$600^{\circ}C$에서 97%의 소결밀도가 얻어졌다.

Yttrium Aluminum Garnet (YAG) powders were synthesized by precipitation of solutions of Al and Y nitrates using ammonium hydrogen carbonate as a precipitant. Y$_2$O$_3$ and YAG phases were formed in the precipitates, which had been attrition-milled. Well-crystallized, phase-pure YAG powders were obtained after calcination of the milled precipitates at 1100$^{\circ}C$ for 1 h. The powders were found to exhibit an excellent sinterability regardless of the addition of SiO$_2$(500 ppm Si) as a sintering aid. All samples already densified to relative densities greater than 70% at 1300$^{\circ}C$ and relative densities of ∼83% at 1400$^{\circ}C$. The samples doped with SiO$_2$ showed a little improvement in densification as compared with those for the undoped samples and resulted in a relative density of 97% at 1600$^{\circ}C$.

키워드

참고문헌

  1. J. Am. Ceram. Soc. v.77 no.11 Phase Development and Luminescence in Chromium-Doped Yttrium Aluminum Garnet (YAG:Cr) Phosphors K.M.Kinsman;J.McKittrick;E.Sluzky;K.Hess https://doi.org/10.1111/j.1151-2916.1994.tb04516.x
  2. J. Phy. Chem. Solids v.60 Photoluminescence Characteristics of YAG:Tb Phosphor Particles with Spherical Morphology and Non-Aggregation Y.C.Kang;I.W.Lenggoro;S.B.Park;K.Okuyama https://doi.org/10.1016/S0022-3697(99)00191-2
  3. Mat. Res. Bull. v.35 Preparation of Cr-Doped $Y_3Al_5O_{12}$ Phosphors by Heterogeneous Precipitation Methods and their Luminescent Properties I.Matsubara;M.Parathaman;S.W.Allison;M.R.Cates;D.L.Beshears;D.E.Holocomb https://doi.org/10.1016/S0025-5408(00)00202-6
  4. Ceram. Eng. Sci. Proc. v.12 no.9-10 High-Temperature Creep of Some Single Crystal Oxides G.S.Corman https://doi.org/10.1002/9780470313848.ch10
  5. Ceram. Eng. Sci. Proc. v.12 no.9-10 High-Temperature Deformation behavior of Polycrystalline Yttrium Aluminum Garnet (YAG) T.A.Parthasarathy;T.Mah;K.Keller https://doi.org/10.1002/9780470313848.ch11
  6. J. Am. Ceram. Soc. v.78 no.1 Fabrication of Polycrystalline Transparent YAG Ceramics by a Solid-State Reaction Method A.Ikesue;I.Furusato;K.Kamata https://doi.org/10.1111/j.1151-2916.1995.tb08389.x
  7. J. Am. Ceram. Soc. v.78 no.4 Fabrication and Optical Properties of High-Performance Polycrystalline Nd:YAG Ceramics for Solid-State Lasers A.Ikesue;T.Kinoshita;K.Kamata;K.Yoshida https://doi.org/10.1111/j.1151-2916.1995.tb08433.x
  8. J. Mater. Res. v.7 no.3 Synthesis of Yttrium Aluminum Garnet by Reverse Strike Precipitation P.Apte;H.Burke;H.Pickup https://doi.org/10.1557/JMR.1992.0706
  9. Kor. J. Ceramics v.1 no.1 Characterization of Spray-Dried Yttrium Aluminum Garnet Powder S.M.Sim
  10. J. Am. Ceram. Soc. v.83 no.4 Low-Temperature Fabrication of Transparent Yttrium Aluminum Garnet (YAG) Ceramics without Additives J.G.Li;T.Ikegami;J.H.Lee;T.Mori https://doi.org/10.1111/j.1151-2916.2000.tb01305.x
  11. J. Eur. Ceram. Soc. v.20 Co-Precipitation Synthesis and Sintering of Yttrium Aluminum Garnet (YAG) Powders: The Effect of Precipitant J.G.Li;T.Ikegami;J.H.Lee;T.Mori;Y.Yajima https://doi.org/10.1016/S0955-2219(00)00116-3
  12. J. Mat. Sci. v.35 Phase Formation in Yttrium Aluminum Garnet Powders Synthesized by Chemical Methods S.M.Sim;K.Keller;T.I.Mah https://doi.org/10.1023/A:1004709401795
  13. Solid State Comm. v.119 Novel Synthesis of $Y_3Al_5O_{12}$ (YAG) Leading to Transparent Ceramics T.Tachiwaki;M.Yoshinaka;K.Hirota;T.Ikegami;O.Yamaguchi https://doi.org/10.1016/S0038-1098(01)00293-9
  14. J. Mater. Sci. v.31 Sol-Gel Processing and Sintering of Yttrium Aluminum Garnet (YAG) Powders R.Manalert;M.N.Rahaman https://doi.org/10.1007/BF00360748
  15. Ceream. Eng. Sci. Proc v.11 Processing and Mechanical Properties of Polycrystalline $Y_3Al_5O_{12}$ K.Keller;T.Mah;T.Parthasarathy https://doi.org/10.1002/9780470313008.ch40
  16. Mater. Res. Bull. v.19 Translucent $Y_3Al_5O_{12}$ Ceramics G.de With;H.J.A.van Dijk https://doi.org/10.1016/0025-5408(84)90245-9
  17. J. Am Ceram. Soc. v.80 no.5 Comparison of Solid-State and Spray-Pyrolysis Synthesis of Yttrium Aluminate Powders M.Nyman;J.Caruso;M.J.Hampden-Smith;T.T.Kodas https://doi.org/10.1111/j.1151-2916.1997.tb02969.x
  18. Mat. Lett. v.39 Synthesis of YAG Phase by a Citrate Combustion Technique S.Roy;L.Wang;W.Sigmund;F.Aldinger https://doi.org/10.1016/S0167-577X(98)00230-4
  19. Powder Tech. v.129 Mechanochemical Solid State Reaction of Yttrium Oxide with Alumina Leading to the Synthesis of Yttrium Aluminum Garnet Q.Zhang;F.Saito https://doi.org/10.1016/S0032-5910(02)00136-5
  20. Mat. Lett. v.56 Low Temperature Formation of Yttrium Aluminum Garnet from Oxides via a High-Energy Ball Milling Process L.B.Kong;J.Ma;H.Huang https://doi.org/10.1016/S0167-577X(02)00480-9
  21. J. Ceram. Soc. Jpn. v.99 no.7 Phase Transformation of Alumina Derived from Ammonium Aluminum Carbonate Hydroxide (AACH) K.Hayashi;S.Toyoda;H.Takebe;K.Morinaga https://doi.org/10.2109/jcersj.99.550
  22. J. Am. Ceram. Soc. v.81 no.8 Fabrication of Transparent Yttria Ceramics at Low Temperature N.Saito;S.Matsuda;T.Ikegami https://doi.org/10.1111/j.1151-2916.1998.tb02583.x
  23. J. Ceram. Proc. Res. v.4 no.3 Synthesis of Yttrium Aluminum Garnet Powder by a Citrate Gel Method B.J.Chung;J.Y.Park;S.M.Sim

피인용 문헌

  1. Characteristics of Porous YAG Powders Fabricated by PVA Polymer Solution Technique vol.534-536, pp.1662-9752, 2007, https://doi.org/10.4028/www.scientific.net/MSF.534-536.21