Journal of Korean Society for Atmospheric Environment (한국대기환경학회지)

Korean Society for Atmospheric Environment (한국대기환경학회)
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Determination of Polycyclic Aromatic Hydrocarbons (PAHs) in Atmospheric Samples by Synchronous 2nd Derivate Spectrofluorimetry

동시형광 분광광도법에 의한 대기 시료 중의 다환방향족 탄화수소(PAHs)의 분석

  • 유광식 (울산대학교 자연과학대학 화학생명과학부) ;
  • 정선이 (울산대학교 자연과학대학 화학생명과학부) ;
  • 정지영 (울산대학교 자연과학대학 화학생명과학부)
  • Published : 2004.02.01
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Abstract

Determination of some PAHs in ambient air at Ulsan have been carried out by collection of the components into n-hexane followed by synchronous spectrofluorimetric technique. 10 PAHs, such as acenaphthene (Ace), anthracene (Anth), benz[a]anthracene (BaA), benzo[b]fluoranthene (BbFt), benzo[k]fluoranthene (BkFt) benzo[a]pyrene (BaP), chrysene (Chry), phenanthrene (Phen), fluoranthene (Ft), perlyrene (Per), and pyrene (Pyr) in air samples were able to determine separately by synchronous spectrofluorimetry. Calibration curves for those components were linear for the concentration range of 0.2∼166ppb PAHs with the correlation factor of 0.9985∼0.9999. The predominant contribution was phenanthrene which was included 36.9∼85.1% to the overall level of the 10 PAHs in some areas. Also benzo[a]pyrene which was known to carcinogenicity was detected from 6.4 to 55.8ng/㎥, benzo[a]anthracene of some areas was contained from 21.9∼153ng/㎥.

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