Enhancement of insecticidal efficacy of acetamiprid soluble concentrates using different adjuvants

서로 다른 보조제에 의한 acetamiprid 액제의 살충활성 증진효과

  • Published : 2004.12.30

Abstract

The studies were undertaken to establish optimum formulation recipes of acetamipid 4% SL(soluble concentrate) using different adjuvants and to evaluate enhanced control effect on target insect pests by adjuvants. Adjuvants for the studies used were SS(Sodium alkylcarboxylate) and PE(Polyoxyethylene alkyl ether). After the fundamental recipe for SL being established by using co-solvent for stability at low temperature, four types of SL were formulated. The physical properties and insecticidal efficacies of the tested SL formulations were investigated. Surface tension of SL1 without adjuvant was highly decreased from 44 dyne/cm to 34 dyne/cm by addition of adjuvants. SL4 using mixed adjuvant showed the lowest contact angle. Efficacies of SL1 without adjuvant against the palm thrips (Thrips palmi) and the cotton aphid (Aphis gossypii) on cucumber were increased by adding adjuvants. SL4 using mixed adjuvant showed higher efficacy than SL2 and SL3 using single adjuvant. These results have demonstrated that the selected adjuvants could be used to enhance insecticide efficacy and reduce spray dose of insecticide.

본 연구는 서로 다른 보조제를 이용하여 살충제인 acetamipid 4% 액제(SL)의 제조처방을 확립하고 생물활성 검정을 통하여 보조제에 의한 살충활성의 증가효과를 검토하고자 수행되었다. 시험에 사용된 보조제는 SS(Sodium alkylcarboxylate)와 PE(Polyoxyethylene alkyl ether) 두가지 였으며, 기초적인 제제시험을 통하여 안정적인 액제 제조처방을 확립하고 선발된 보조제를 이용하여 각기 다른 4가지 제조처방을 가진 시제품을 제조하여 시험에 사용하였다. 각각의 시제품은 보조제 특성을 평가하기 위하여 기본적인 물리성을 측정하였고 오이를 대상으로 오이총채벌레(Thrips palmi) 및 목화진딧물(Aphis gossypii)에 대한 살충 활성을 비교하였다. 보조제가 첨가되지 않은 SL1의 경우, 보조제를 첨가하면서 표면장력이 44 dyne/cm에서 34 dyne/cm으로 감소하였고 접촉각은 SS와 PE의 혼합 보조제를 사용한 SL4에서 가장 낮은 값을 나타내었다. 오이 총채벌레 및 목화진딧물에 대한 살충활성은 보조제를 첨가함에 따라 증가하였고 단독 보조제를 사용한 SL2와 SL3보다는 SS와 PE의 혼합 보조제를 사용한 SL4에서 가장 우수한 활성을 나타내었다. 이상의 결과는 적절한 보조제의 선발에 의하여 살충제의 활성을 증가시킬 수 있고 이를 통하여 살충제의 처리량을 줄일 가능성이 있음을 보여주고 있다.

Keywords

References

  1. Abbott, W. S. (1925) A method of computing the effectiveness of an insecticide. J. Econ. Entomol. 18:265-267
  2. Aven, M., G. Noga and M. Reuter (1998) Effect of alcohol ethoxylate surfactants on the penetration and efficacy of the fungicide dimethomorph in grapevine leaves. pp.176-181, In Proceeding of 5th International Symposium on Adjuvants for Agrochemicals (ed. P. M. McMullan), Memphis, USA
  3. Dobrat, W. and A. Martijn (1995) CIPAC Handbook vol. F - Physico-chemial methods for technical and formulated pesticides, Collaborative International Pesticides Analytical Council Ltd., UK
  4. Ford, M. G. and D. W. Salt (1987) Behaviour of insecticide deposits and their transfer from plant to insect surfaces. pp.26-81, In Pesticides on Plant Surfaces -Critical reports on applied chemistry vol. 18 (ed. H.J. Cottrell), John Wiley & Sons, UK
  5. Foy, C. L. (1998) The challenges and opportunities of adjuvants and biological performance. pp.155-169, In Proceeding of 5th International Symposium on Adjuvants for Agrochemicals (ed. P. M. McMullan), Memphis, USA
  6. Gaskin, R. E. and R. J. Murray (1998) Adjuvants to improve insecticidal activity of diazinon on kiwifruit. pp.217-222, In Proceeding of 5th International Symposium on Adjuvants for Agrochemicals (ed. P. M. McMullan), Memphis, USA
  7. Green, J. M. (2001) Factors that influence adjuvant performance. pp.179-190, In Proceeding of 6th International Symposium on Adjuvants for Agrochemicals ISAA 2001 (ed. Hana de Ruiter), Amsterdam, The Netherlands
  8. Holloway P. J. (1998) Improving agrochemical performance : possible mechanisms for adjuvany. pp.232-263, In Chemistry and Technology of Agrochemical Formulations (ed. D. A. Knowles), Kluwer Academic Publishers, UK
  9. Knowles, D. A. (1998) Formulation of agrochmicals. pp.44-45, In Chemistry and Technology of Agro chemical Formulations (ed. D. A. Knowles), Kluwer Academic Publishers, UK
  10. Mulqueen P. J. (1998) Safer formulations of agrochemicals. pp.121-157, In Chemistry and Technology of Agrochemical Formulations (ed. D. A. Knowles), Kluwer Academic Publishers, UK
  11. Nalewaja, J.D. and R. Matysiak (2001) Linear alchol ethoxylate surfactants with nicosuluron. pp.209-217, In Proceeding of 6th International Symposium on Adjuvants for Agrochemicals ISAA 2001 (ed. Hana de Ruiter), Amsterdam, The Netherlands
  12. Reekmans, S. (1998) Novel surfactants and adjuvants for agrochemicals. pp.212-231, In Chemistry and Technology of Agrochemical Formulations (ed. D. A. Knowles), Kluwer Academic Publishers, UK
  13. Thomas, J. M., F. Yopp and T. Clark (1998) Enhancement of insecticide efficacy by novel adjuvants. pp.347-351, In Proceeding of 5th International Symposium on Adjuvants for Agrochemicals (ed. P. M. McMullan), Memphis, USA
  14. Tomlin, C. D. S. (2003) The Pesticide Manual (13th edition). British Crop Protection Council, Survey, UK, pp.7-8
  15. 농약공업협회 (2004) 2004 농약사용지침서. pp.400~402, 농약공업협회,한국
  16. 농업과학기술원 (1996) 농약의 검사방법. pp.3-7, 농업과학기술원고시 제1996-2호