Bulletin of the Korean Chemical Society

  • 제25권9호
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  • Pages.1309-1313
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  • 2004
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  • 0253-2964(pISSN)
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  • 1229-5949(eISSN)
대한화학회 (Korean Chemical Society)
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Flame Atomic Absorption Spectrometric Determination of Ultra Traces of Thallium(I) ion after Solid Phase Extraction by Octadecyl Silica Membrane Disk Modified by a New Schiff Base

  • 발행 : 2004.09.20
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초록

A simple and reliable method has been developed to selectively separate and concentrate trace amounts of thallium ion from real samples for the subsequent measurement by flame atomic absorption spectrometry (FAAS). Thallium ions are absorbed quantitatively during passage of aqueous real samples through an octadecyl bonded silica membrane disk modified by 4-(4-Chloro-phenylazo)-2-[(4-hydroxy-phenylamino)-methyl]-phenol. The retained $Tl^+$ ions are then stripped from the disk quantitatively with a minimal amount of thiosulfate solution as eluent. The proposed method permitted large enrichment factors of about 130 and higher. The relative standard deviation for ten replicate extraction of thallium from 1 L samples containing 5 ${\mu}g$ thallium is 1.2%. The break through volume for 5 ${\mu}g$ thallium is 1000 mL. The limit of detection of the proposed method is 11.2 ng of $Tl^+$ per 1000 mL. The effects of various cationic interferences on the recovery of thallium in binary mixtures were studied. The method was applied to the recovery of $Tl^+$ ions from natural water and human hair samples.

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피인용 문헌

  1. -phenylenediamine and Determination by Spectrophotometry vol.26, pp.10, 2008, https://doi.org/10.1002/cjoc.200890330
  2. Speciation and determination of thallium by on-line microcolumn separation/preconcentration by flow injection-flame atomic absorption spectrometry using immobilized oxine as sorbent vol.148, pp.1, 2004, https://doi.org/10.1016/j.jhazmat.2007.02.059