Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Epinephrine-Selective Electrode Based on Lipophilic 1,3-Bisbridged Cofacial-calix[6]crown-5-ether

  • Yeo, Hee-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National Univerisity) ;
  • Lee, Hyo-Kyoung (Department of Chemistry and Institute of Basic Science, Chonnam National Univerisity) ;
  • Nam, Kye-Chun (Department of Chemistry and Institute of Basic Science, Chonnam National Univerisity) ;
  • Jeon, Seung-Won (Department of Chemistry and Institute of Basic Science, Chonnam National Univerisity)
  • Published : 2004.03.20
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Abstract

The potentiometric response of electrode no. 4 based on 1,3-bisbridged cofacial-calix[6]crown-5-ether (IV) gave a sub-Nernstian (45.0 mV/decade) response and the best detection limit (-log $a_{ep}$ = 4.73) towards epinephrine. The responses are decreasing in the order of epinephrine > $K^+$, dopamine > $NH_4^+$ > norepinephrine > $Na^+$. It is remarkable that the proposed electrode shows the reasonable selectivity to epinephrine against other catecholamine neurotransmitters (dopamine and norepinephrine) as well as alkali metal ions.

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References

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