Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Study of the Potential Interference of ArC+ on the Direct Determination of Trivalent Chromium and Hexavalent Chromium Using Ion Chromatography Coupled with ICP-MS

  • Nam, Sang-Ho (Department of Chemistry, Mokpo National University) ;
  • Park, Young-Il (Department of Chemistry, Mokpo National University) ;
  • Kim, Jae-Jin (Department of Chemistry, Mokpo National University) ;
  • Han, Sun-Ho (Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute) ;
  • Kim, Won-Ho (Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute)
  • Published : 2004.04.20
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Abstract

Low and high resolution inductively coupled plasma mass spectrometry (ICP-MS) coupled with ion chromatography (IC) has been investigated for speciation of Cr(III) and Cr(VI). In particular, the interference of ArC^+formed by the carbon in a sample on the simultaneous determination of Cr(III) and Cr(VI) has been studied. In chemical speciation, this study shows that quadrupole type ICP-MS with low resolution has a limitation of simultaneous determination fo chromium species if the sample contains the carbon elements. The interference problems can be solved by high resolution ICP-MS.

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