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Ammonia Gas-sensing Characteristics of $Cr_{2}O_{3}$ Thick Films

$Cr_{2}O_{3}$ 후막의 암모니아 가스 감지 특성

  • Cho, Chul-Hyung (Chip pack Co.) ;
  • Park, Ki-Cheol (Department of Electrical & Electronic Engineering and RICIC, Gyeongsang National University) ;
  • Ma, Tae-Young (Department of Electrical & Electronic Engineering and RICIC, Gyeongsang National University) ;
  • Kim, Jeong-Gyoo (Department of Electrical & Electronic Engineering and RICIC, Gyeongsang National University)
  • 조철형 (칩팩(주)) ;
  • 박기철 (경상대학교 전기전자공학부 및 RICIC) ;
  • 마대영 (경상대학교 전기전자공학부 및 RICIC) ;
  • 김정규 (경상대학교 전기전자공학부 및 RICIC)
  • Published : 2004.11.30

Abstract

$Cr_{2}O_{3}$ thick films were fabricated by screen printing method on alumina substrates and annealed at $700^{\circ}C$, $800^{\circ}C$, and $900^{\circ}C$ in air, respectively. Structural properties examined by XRD and SEM showed (116) dominant $Cr_{2}O_{3}$ peak and increased grain sizes with the annealing. The resistance of the films decreased with increasing the annealing temperature. Gas sensing characteristics to $NH_{3}$, CO, $C_{4}H_{10}$, and NO gases showed sensitivity only to $NH_{3}$ gas. $Cr_{2}O_{3}$ thick films annealed at $700^{\circ}C$ had the sensitivity of about 15 % for 100 ppm $NH_{3}$ gas at the working temperature of $300^{\circ}C$. The thick films had good selectivity to the $NH_{3}$ gas. The response time to $NH_{3}$ gas was about 10 seconds.

Keywords

References

  1. S. Christie, E. Scorsone, K. Persaud, and F. Kvasnik, 'Remote Detection of Gaseous Ammonia using the Near Infrared Transmission Properties of Polyaniline', Sensors and Actuators B, vol. 90, pp. 163-169, 2003 https://doi.org/10.1016/S0925-4005(03)00036-4
  2. 성명권, 박정수, 최신센서공학, 한동, pp.91-99, 1998
  3. G. Sberveglieri, 'Recent Developments in Semiconducting Thin-film Gas Sensors', Sensors and Actuators B, vol. 23, pp. 103-109, 1995 https://doi.org/10.1016/0925-4005(94)01278-P
  4. G. Sberveglieri, S. Groppelli, P. Nelli, A. Tintinelli, and G. Giunta, 'A Novel Method for the Preparation of $NH_3$ Sensors Based on ZnO-In Thin Films', Sensors and Actuators B, vol. 25, pp. 588-590, 1995 https://doi.org/10.1016/0925-4005(95)85128-3
  5. 김진해, 전춘배, 박기철, 'ZnO:In 박막 $NH_3$ 가스센서의 제작 및 그 특성', 센서학회지, 제8권 제3호, pp.274-281, 1999
  6. 김성우, 최우창, 최혁환, 이명교, 권태하, '$MoO_3$ 를 첨가한 ZnO 박만센서의 암모이나 가스 검지 특성', 센서학회지, 제8권 제1호, pp.24-31, 1999
  7. P. Lauque, M. Bendahan, C. Jacolin, J.-L. Seguin, M. Pasquinelli, and P. Knauth, 'Electrical Properties and Sensor Characteristics for $NH_3$ Gas of Sputtered CuBr Films', Sensors and Actuators B, vol. 59, pp. 216-219, 1999 https://doi.org/10.1016/S0925-4005(99)00223-3
  8. C. Imawan, F. Solzbacher, H. Steffes, and E. Obermeier, 'Gas-Sensing Characteristics of Modified $MoO_3$ Films using Ti-Overlayers for $NH_3$ Gas Sensors', Sensors and Actuators B, vol. 64, pp. 193-197, 2000 https://doi.org/10.1016/S0925-4005(99)00506-7
  9. L. Chambon, C. Maleysson, A. Pauly, J. P. Germain, V. Demame, and A. Grisel, 'Investigation, for $NH_3$ Gas Sensing Application, of the $Nb_2O_5$ Semiconducting Oxide in the Presence of Interferent Species such as Oxygen and Humidity', Sensors and Actuators B, vol. 45, pp. 107-114, 1997 https://doi.org/10.1016/S0925-4005(97)00281-5
  10. S. Sen, K. P. Muthe, N. Joshi, S. C. Gadkari, S. K. Gupta, Jagannath, M. Roy, S. K. Deshpande, and J. V. Yakhmi, 'Room Temperature Operating Ammonia Sensor Based on Tellurium Thin Films', Sensors and Actuators B, vol. 98, pp. 154-159, 2000
  11. G. S. Trivikrama Rao and D. Tarakarama Rao, 'Gas Sensitivity of ZnO Based Thick Film Sensors to $NH_3$ at Room Temperature', Sensors and Actuators B, vol. 55, pp. 166-169, 1999 https://doi.org/10.1016/S0925-4005(99)00049-0
  12. S. S. Sunu, E. Prabhu, V. Jayaraman, K. I. Gnanasekar, T. K. Seshagiri, and T. Gnanasekaran, 'Electrical Conductivity and Gas Sensing Properties of $MoO_3$', Sensors and Actuators B, vol. 101, pp. 161-174, 2004 https://doi.org/10.1016/j.snb.2004.02.048
  13. X. Wang, N. Miura, and N. Yamazoe, 'Study of $WO_3$-Based Sensing Materials for $NH_3$, and NO Detection', Sensors and Actuators B, vol. 66, pp. 74-76, 2000 https://doi.org/10.1016/S0925-4005(99)00410-4
  14. 윤동현, 권철환, 홍형기, 김승렬, 이규정, '후막형 암모니아 가스센서의 제조 및 가스 감응 특성', 센서학회지, 제6권 제6호, pp. 445-450, 1997
  15. T. G. Nenov and S. P. Yordanov, Ceramic sensors, Technomic, 1996
  16. 김준곤, 안병렬, 마대영, 박기철, 김정규, '$AI_2O_3$를 첨가한 $LaFeO_3$ 후막의 암모니아 가스 감지특성', 센서학회지, 제11권 제1호, pp. 18-27, 2002