Chemical-looping combustion을 위한 단일금속산화물인 산소운반체에 관한 연구

Study of Oxygen Carriers with Single Metal Oxides for Chemical-Looping Combustion

  • 이진배 (한국에너지기술연구원) ;
  • 박주식 (한국에너지기술연구원) ;
  • 최상일 (한국에너지기술연구원) ;
  • 송영욱 (충남대학교 대학원 공업화학과) ;
  • 양현수 (충남대학교 대학원 공업화학과) ;
  • 김영호 (충남대학교 대학원 공업화학과)
  • Lee, J.B. (Korea Institute of Energy Research) ;
  • Park, J.S. (Korea Institute of Energy Research) ;
  • Choi, S.I. (Korea Institute of Energy Research) ;
  • Song, Y.W. (Department of Fine Chemicals Engineering & Chemistry, Chung-nam national university) ;
  • Yang, Y.S. (Department of Fine Chemicals Engineering & Chemistry, Chung-nam national university) ;
  • Kim, Y.H. (Department of Fine Chemicals Engineering & Chemistry, Chung-nam national university)
  • 발행 : 2003.09.15

초록

A new kind of oxygen carrier material is tested for chemical-looping combustion. NiO, CoO, $Fe_2O_3$ is chosen as metal oxide and YSZ as a binder. Hydrogen fuel is reacted with metal oxide (reduction of metal oxide) and then the reduced metal is successively oxidized by air. Dissolution method is examined to prepare the oxygen carriers. The effects of reaction temperature are measured by a TGA, mechanical strength and regenerability after 10 cycle are examined. $Fe_2O_3/YSZ$ oxygen carrier is bested in mechanical strength and we consider that NiO/YSZ after 3rd cycle are good oxygen carrier in according to reactor design.

키워드

과제정보

연구 과제 주관 기관 : 에너지기술연구원

참고문헌

  1. Lundberg, G., 'The Future of FossilFuel in Power Plants', Proceedings ofthe Florence World Energy ResearchSymposium Firenze, Italy, 1990, pp. 3-20
  2. Riemer, P. Greenhouse Gas MitigationTechnologies, an Overview of the $CO_2$ Capture, Storage and Future Activities of the IEA Greenhouse Gas R&D Programme. Energy Convers Mgmt. Vol.37, 1996, pp. 665-670 https://doi.org/10.1016/0196-8904(95)00237-5
  3. M. Ishida, H. Jin. "A Novel Chemical -Looping Combustor without NOx Formation", Industrial Engineering Chemical Research, Vol. 35, 1996, pp. 2469-2472 https://doi.org/10.1021/ie950680s
  4. Richter, H. J. and K. F. Knoche, "Reversibility of Combustion Process", ACS Symposium Series, 235, R.A. Gaggioli, de., Washington, D.C., 1983, pp. 71-85 https://doi.org/10.1021/bk-1983-0235.ch003
  5. M. Ishida, H. Jin, "A New Advanced Power-generation System Using Chemical-looping Combustion", Energy The International Journal, Vol.19, 1994, pp. 415-422 https://doi.org/10.1016/0360-5442(94)90120-1
  6. M. Ishida, H. Jin, "A Novel Combustor Based on Chemical-looping Reactions and its Reaction Kinetics", Chemical Engineering of Japan, Vol. 27, 1994, pp.296-301 https://doi.org/10.1252/jcej.27.296
  7. M. Ishida, H. Jin, T. Okamoto, "Kinetic Behavior of Solid Particle in Chemical Looping Combustion: Suppressing Carbon Deposition In Reduction", Energy &Fuels, Vol. 12, 1998, pp. 223-229 https://doi.org/10.1021/ef970041p
  8. M. Ishida, H. Jin and T. Okamoto, "A Fundamental Study of a New Kind of Medium Material for Chemical-Looping Combustion", Energy & Fuels, Vol. 10, 1996, pp. 958-963 https://doi.org/10.1021/ef950173n