A Comparison of Corrosion Performance of Zirconium Grain Refined MEZ and AZ91 Alloys

  • Song, Guangling (CRC for Cast Metals Manufacturing (CAST) Department of Mining, Minerals and Materials Engineering, The University of Queensland) ;
  • StJohn, David (CRC for Cast Metals Manufacturing (CAST) Department of Mining, Minerals and Materials Engineering, The University of Queensland)
  • Published : 2003.02.01

Abstract

In this study, sand cast AZ91E and zirconium grain refined MEZ are representative of two typical groups of magnesium alloys: those containing aluminium and those containing no aluminium but with zirconium as a grain refiner. The corrosion performance of these two alloys was evaluated and compared in 5%wt NaCI solution through measurements of weight loss and polarisation curves and examination of microstructure. Corrosion damage of AZ91E was deeper and more localised than that of MEZ, while MEZ had a lower rate of cathodic hydrogen evolution and a higher rate of anodic dissolution than AZ91E. These differences in behaviour can be related to the differences in microstructure and chemical composition between the two alloys.

Keywords

Acknowledgement

Supported by : University of Queensland

References

  1. O. Lunder, K. Nisancioglu, and R. S. Hansen, ‘Corrosion of Die Cast Magnesium-Aluminum Alloys’, SAE Technical Paper Series#930755, Detroit, (1993)
  2. G. L. Makar and K. Kruger, J. Electrochem. Soc., 137, 414 (1990)
  3. C. B. Baliga and P. Tsakiropoulos, Materials Science and Technology, 9, 513 (1993)
  4. E. F. Emley, ‘Principles of Magnesium Technology’, Chapter XX, (1966)
  5. D. S. Tawil, ‘Protection of Magnesium Components in Military Applications’, Paper No. 90445, NACE '90 Conference, Las Vegas, (1990)
  6. G. Song and O. StJohn, ‘The Effect of Zirconium Grain Refinement on the Corrosion Behaviour of Magnesium-Rare Earth Alloy MEZ’, CAST Report
  7. G. Song and O. StJohn, ‘An hydrogen evolution method for the estimation of the corrosion rate of magnesium alloy’, John N. Hryn, ed. Magnesium Technology 2001, TMS pp.255-262 (2001)
  8. C. J. Bettles and C. T. Forwood (compiled), ‘Identification of a Creep Resistant Magnesium Alloy for the Manufacture of Engine Blocks’ CAST internal confidential report. (1998)
  9. G. Song, A. Atrens, X. Wu, and B. Zhang, Corrosion Science, 40(10), 1769 (1998)
  10. M. Dargusch, 'Elevated temperature deformation of diecast Mg alloy AZ91D', in G. W. Lorimer (ed), 'Proceedings of the Third International Magnesium Conference', Manchester, UK, April, 1996, pp.153-165
  11. O. Lunder, J. E. Lein, T. Kr. Aune, and K. Nisancioglu, Corrosion, 45(9), 741
  12. I. Nakatsugawa, S. Kamado, Y. Kojima, R. Ninomiya, and K. Kubota, ‘Corrosion Behaviour of Magnesium Alloys Containing Heavy Rare Earth Elements’, in G.W.Lorimer (ed) ‘Proceedings of the Third International Magnesium Conference’, Manchester, pp.687-698, (1996)