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Prediction of Carbonation Progress for Concrete Structures Considering Change of Atmospheric Environment

대기환경변화를 고려한 콘크리트 구조물의 중성화 예측

  • Lee, Chang-Soo (Dept. of Civil Engineering, The University of Seoul) ;
  • Yoon, In-Seok (Dept. of Civil Engineering, The University of Seoul)
  • 이창수 (서울시립대학교 토목공학과) ;
  • 윤인석 (서울시립대학교 토목공학과)
  • Published : 2003.08.01

Abstract

The most common deterioration cause of concrete structures in urban environment is carbonation. Recently, the $CO_2$ concentration and temperature at atmosphere is sharply increased with time due to global warming phenomena. In this study, the climate scenario IS92a, which was suggested by the IPCC, is used to consider temperature and atmospheric $CO_2$ concentration change in the model of service life prediction. The modified mathematical solution, which was based on the Fick's 1st law of diffusion, was used to reflect concrete materials properties such as the degree of hydration of concrete with elapsed time, and important parameters, which associated with deterioration rate. The techniques of service life prediction are developed introducing the method of reliability and stochastic concept to consider microclimatic condition in Seoul, South Korea. From the result of service life prediction, concrete containing high W/C ratio is shown fast carbonation rate due to $CO_2$ concentration increase. It is concluded that the deterioration of concrete structures due to carbonation is insignificant problem on the conditions that below W/C 55%, well curing concrete.

도심지 환경에서 콘크리트 구조물의 열화를 일으키는 주요한 요인 중 하나는 중성화이다. 최근, 대기 중 $CO_2$농도와 온도가 크게 증가하는 지구 온난화 현상으로 인하여 중성화 열화환경도 더욱 심각해지고 있다. 본 연구에서는 IPCC에서 제안한 지구규모 대기환경 변화 시나리오인 IS92a를 토대로 향후 100년까지 대기 중 $CO_2$ 농도와 온도 상승율을 예측하였다. 질량보존의 법칙과 Fick의 1법칙을 기초방정식으로 하여 시간경과에 따른 콘크리트의 수화도, 콘크리트 열화에 미치는 각종 주요변수 등의 재료물성을 반영하였다. 또한, 서울시의 미세기후조건을 반영하기 위하여 추계학적 및 통계학적 기법을 도입하여 중성화로 인한 내구수명예측 기법에 반영하였다. 연구결과에 의하면 물-시멘트비가 큰 콘크리트에서 COS 농도증가로 인한 중성화 진행속도가 뚜렷히 빨라지는 것으로 나타났다. 그러나 물-시멘트비 55% 이하에서 충분히 양생된 보통 포틀랜드 콘크리트의 조건에서 중성화에 대한 우려가 높지 않을 것으로 생각된다.

Keywords

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