오리나무 열매를 이용한 생물처리장치에서의 톨루엔 가스 처리효율 특성

Characterization of Toluene Vapor Removal Efficiency Using Alnus Firma Fruit in a Biological Treatment Process

  • 발행 : 2003.12.01

초록

This study was to examine characteristics of treating toluene vapor, which gets to be problematic due to its harmful carcinogenicity and mass generation from various sources, through a biological treatment facility which is environment-friendly and adopts a high-efficient and low-cost clean technology. In order to identify whether Alnus Firma Fruit (AFF) can be used as a media for a bioreactor, its utility and basic operating factors, a study was conducted on pressure drop, supply of nutrient substances and retention time which are operating factors of a biofilter, and eliminating characteristics were compared between AFF and the conventional biological activatedcarbon (BAC) widely used as filter media. In the case of AFF, the initial microbial deposits was 2.3${\times}$10$^{7}$ CFU/g dry AFF, which represents the initial microbial density higher than the case of BAC showing 5.5${\times}$10$^{6}$ CFU/g dry BAC And it took about 2 weeks to acclimate until its eliminating rate got to be increased over 90%. As a result of comparing pressure loss taking place with the lapse of time between BAC and AFF, after 130 days passed at SV 25h$^{-1}$ , BAC showed that its eliminating efficiency had a tendency to drop greatly due to a great pressure loss (0.53\longrightarrow54.7 mm$H_2O$/m) caused by an excess of biomass as accumulated. On the other hand. AFF showed that the pressure drop was 0.53 mm$H_2O$/m, about 2 times as much as the initial pressure loss of 0.4 mm$H_2O$/m, which represents no great change in the pressure loss, and its eliminating efficiency was also shown to be continuously high. Therefore, when AFF was used as a filler for a biological treatment facility, a biological filter enabling improvement of the purifying efficiency to be promoted could be provided, and moreover, the pressure loss was so small that the filler replacement cycle or the back flushing cycle could be extended. So, even in terms of the operating cost, it was identified to be an economical filler When an inorganic material was used as a filler, the biofilters performance acted sensitively on whether nutrient substances were supplied or not. In the case of AFF with low adsorptivity, addition of ethyl-alcohol increased the solubility of toluene, and consequently, biodegradation got to be actively made by microbes, and thus, its eliminating rate could be increased. As the flow velocity and the inflow concentration got to be more increased, its eliminating rate got to be lower, and particularly, an increase in the flow velocity made its eliminating rate drop more greatly than an increase in the concentration.

키워드

참고문헌

  1. 강신묵(1999) 생물활성탄과 부식토를 이용한 툴루엔 가스 제거, 동아대학교 박사학위논문
  2. 김종오, 이우범 (2001) Biofilter에 의한 Benzene 가스의 처리, 대한환경공학회지, 23 (5), 831-838
  3. 박상곤(1999) 흡착법을 이용한 공기 중 휘발성유기화함몰 의 측정방법론 평가 빛 현장적 용에 관한 연구, 영남대학교 박사학위논문
  4. 박상진 (2001) 악취 빛 VOCS 제거를 위한 G-7 Biofilter의 개발 빛 실용화 사례, 첨단환 경기술, 10-23.
  5. 염승호, 최석순(1998) Klebsiella gr .47을 이용한 생물학적 폐수처리에서 BTX 분해 특성, 한국환경과학회지, 7(3),393-400
  6. 임재신 (2001) Biological Trickling Filter를 이용한 VOCS 처 리에 있어서 공기병용 역셰 척에 의한 잉여미생물 제거, 한국과학기술원 박사학위논문
  7. 福山 文二(1999) 充鎭搭式生物脫莫法によるトルエン昊 氣の除去.J. Oder Research and Eng., 30(4), 202208
  8. 山下 茂樹,北川 政美(1999) 生物處理裝置による排ガス 中トルエンの分解, J. Oder Research and Eng. , 30(4),197-201
  9. 太田口和久高山(1999) トルエン生分解反應特性の評價.J. Oder Research and Eng., 30(4), 209-213
  10. Altaf, H. Wani, Richard M.R., Branion, and Anthony K. Lau (1997) A Promising and cost-effective control technology for odors, VOCS and air toxics, J. Environ. Sci. Health, A32(7), 2027-2055
  11. Lehning, A., U. Fock, R.M. Wittich, K.N. Timmis, and D.H. Pieper (1997) Metabolism of chlorotoluenes by Burkholderia sp. strain P1: Evidence for monoxygenation by toluene and chlorobenzene dioxygenase, Appp.Microbiol., 5, 1974-1979
  12. Chou, Ming-Shean and Feh-Loong Wu (1999) Treatment of toluene in an air stream by biotrickling filter packed with slags, J. Air & Waste Manage. Assoc., 49, 386 -398
  13. Chung, Y.C., C. Huang, and C.T. Tseng (1996) Operation optimization of Thiobacillus thioparus CHII biofilter for hydrogen sulfide removal, J. iotechnology, 52,31-38
  14. George A. Sorial, Francis L. Smith, Makram T. Suidan, and Pratim Biswas (1995) Evaluation of trickle bed biofilter media for toluene removal, J. Air & Waste Manage. Assoc., 45, 801-810
  15. Kirchner, K., U. Schlachter, and H.J. Rehm (1989) Biological purification of exhaust air using fixed bacterial monocultures, Appl Micro Biotechnol, 31, 629-632 https://doi.org/10.1007/BF00270808
  16. Ottengraf, S.S.P. and A.H.C. Van den Oever (1983) Kinetics of organic removal from waste gases with a biological filter, Biotechnol. Bioeng., 25, 3089
  17. Sorial, G.A. and F.L. Smith, M.T. (1997) Evaluation of trickle bed air biofilter performance for BTEX rerno val, J. Environmental Engineering, 6, 530-537
  18. Van Langenhove, H., E. Wuyts and N, Schamp (1986) Elimination of hydrogen sulfide from odorous air by a wood bark biofilter, Wat. Res., 20, 1471-1476
  19. Yang, Y. and E.R. Allen (1994) Biofiltration control of hydrogen sulfide, J. Air & Waste Manage. Assoc., 47, 37-48