Korean Membrane Journal

한국막학회 (The Membrane Society of Korea)
권호 표지

Sulfonated Dendrimers for the Application of Fuel Cell Membranes 1. Synthesis and Characterization of Sulfonated Dendrimers

  • 발행 : 2003.12.01
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초록

1,3,5-Sustitituted polyphenylene type dendrimers were synthesized. The dendrimer was heated in cone. H$_2$SO$_4$ at 120$^{\circ}C$. The reaction mixture was precipitated to ether after simple filtration to get para-sulfonated dendrimer as the chief product. To give mechanical properties to the sulfonated dendrimer, it was partially cross-linked with phenyl ether in the medium of P$_2$O$\sub$5/ and CH$_3$SO$_3$H.

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참고문헌

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  3. (a) P. E. Eaton, G. R. Carlson, and J. T. Lee, 'Phosphorus pentoxide-methanesulfonic acid. Convenient alternative to polyphosphoric acid,' J. Org. Chem., 38, 4071-4073 (1973)
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  5. H.-J. Kim, S. Y. Nam, M. H. Lin, and E.-M. Shin, 'Synthesis and Characterization of Sulfonic Acid Containing Polyimide Electrolyte Membranes(PEMs),' Macromol. Res. Accepted