Journal of Photoscience

한국광과학회 (Korean Society of Photoscience)
권호 표지

$TiO_2$-Mediated Photoreactions of Cinnamic Acid and Related Compounds in Methanol

  • Kim, Sung-Sik (Department of Chemistry, Chonbuk National University) ;
  • Kim, Hyun-Jin (Department of Chemistry, Chonbuk National University) ;
  • Lee, Hye-Jong (Department of Chemistry, Chonbuk National University) ;
  • Park, Sang-Kyu (Department of Chemistry, Chonbuk National University)
  • 발행 : 2003.08.01
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초록

Photochemical reactions of some organic molecules on titanium dioxide were investigated in methanol. A methanolic solution of trans-cinnamic acid and titanium dioxide was irradiated with 300 nm UV lamps for 24 h to afford methyl cinnamate. In the case of trans-cinnamamide, the major product was found to be 3-phenylpropionamide, i.e., a saturation product of ethylenic double bond. However, irradiation of urocanic acid, caffeic acid, ethyl cinnamate, trans-chalcone, trans-cinnamonitrile, trans-stilbene or trans, trans-1,4-diphenyl-1,3-butadiene on titanium dioxide under the same conditions did not give any noticeable products. Meanwhile, when irradiated some aromatic aldehydes, such as trans-cinnamaldehyde, l-naphthaldehyde, and 2-naphthaldehyde in methanol, vicinal diols and alcohols derived from the diols were produced. On the other hand, irradiation of 9-anthraldehyde and titanium dioxide in methanol afforded only alcohols, in which diol was not observed.

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참고문헌

  1. Journal of Photochemistry and Photobiology C v.1 no.1 Titanium dioxide photocatalysis Fujishima,A.;T.N.Rao;D.A.Tryk
  2. Applied Catalysis v.8 no.2 Titanium oxide based catalysts Matsuda,S.;A.Kato
  3. Chemosphere v.48 no.10 Heterogeneous water phase catalysis as an environmental application Kari Pirkanniemi,K.;M.Sillanpaa
  4. Water Research v.37 no.2 Catalytic wet oxidation of phenol in a trickle bed reactor over a Pt/TiO₂catalyst Maugans,C.B.;A.Akgerman
  5. Journal of Catalysis v.211 no.2 Selective oxidation of alcohols in gas phase using light-activated titanium dioxide Pillai,U.R.;E.Sahle-Demessie
  6. Journal of Photochemistry and Photobiology A: Chemistry v.152 no.1-3 Selective oxidation of selected fluorenols on TiO₂semiconductor Mohamed,O.S.
  7. Journal of Catalysis v.207 no.2 Acetic acid reduction by H₂over supported Pt catalysis: A DRIFTS and TRD/TPR Study Rachmady,W.;M.A.Vannice
  8. Catalysis Today v.73 no.1-2 Catalytic activities of nickel-containing catalysts for ethylene dimerization and butene isomerization and their relationship to acidic properties Sohn,J.R.
  9. European Polymer Journal v.36 no.10 Polymerization of bismaleimide and maleimide monomers catalyzed by nanometer sized $Na^+$/TiO₂ Liu,X.;D.Chen;X.Yang;L.Lu;X.Wang
  10. Applied Catalysis A v.148 no.2 Effect of metal support interaction during selective hydrogenation of cinnamaldehyde to cinnamyl alcohol on platinum based bimetallic catalysts da Silva;A.B.;E.Jordao;M.J.Mendes;P.Fouilloux
  11. Journal of Organic Chemistry v.57 no.19 Photoinduced reduction of aldehydes on titanium dioxide Joyee-Pruden,C.;J.K.Pross;Y.Li