Fabrication of $SnO_2$ Gas Sensor added by Metal Oxide for DMMP

DMMP 검출용 금속산화물을 첨가한 $SnO_2$ 가스센서 제조

  • 최낙진 (경북대학교 전자공학과 대학원) ;
  • 반태현 (경북대학교 센서공학과) ;
  • 곽준혁 (경북대학교 전자공학과 대학원) ;
  • 백원우 (경북대학교 금속공학과) ;
  • 김재창 (경북대학교 화학공학과) ;
  • 허증수 (경북대학교 금속공학과) ;
  • 이덕동 (경북대학교 전자전기공학부)
  • Published : 2003.09.01

Abstract

$SnO_2$ gas sensor for the detection DMMP, simulant of nerve gas was fabricated and its characteristics were examined. Sensing materials were $SnO_2$ added by TEX>$\alpha$-$Al_{2}O_{3}$ with 0∼20wt.% and $In_{2}O_{3}$ with 0∼3wt.% and were physically mixed each material. They were deposited by screen printing method on alumina substrate. The sensor was consisted of sensing electrode with interdigit(IDT) type in front and a heater in back side. Its dimension was 7$\times$10$\times$0.6$\textrm{mm}^2$. Crystallite size 8t phase identification, specific surface area and morphology of fabricated $SnO_2$ powders were analyzed by X-ray diffraction(XRD), surface area analyzer(BET) and by a scanning electron microscope(SEM), respectively. Sensor was measured as flow type and sensor resistance change was monitored as real time using LabVIEW program. The best sensitivities were 75% at adding 4wt.% TEX>$\alpha$-$Al_{2}O_{3}$, operating temperature $300^{\circ}C$ and 87% at adding 2wt.% $In_{2}O_{3}$, operating temperature $350^{\circ}C$ to DMMP 0.5ppm. Response and recovery times were about 1 and 3 min., respectively. Repetition measurement was very good with $\pm$3% in full scale. As a result, operating temperature was lower TEX>$\alpha$-$Al_{2}O_{3}$ than $In_{2}O_{3}$, but sensitivity was higher $In_{2}O_{3}$ than $\alpha$-$Al_{2}O_{3}$.

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