온도변화에 따른 AISI 304SS의 틈내 전위강하에 관한 연구

A Study on the IR Drop in Crevice of AISI 304 Stainless Steel by Temperature Variation

  • 발행 : 2003.11.01

초록

As the results of recent industrial development, many industrial plants and marine structures are exposed to severe corrosion environment than before. Especially, under the wet environment, crevice corrosion damage problems necessarily occur and encourage many interests to prevent them. In this study, the electrochemical polarization test was carried out to study characteristics of crevice corrosion for AISI 304 stainless steel in various solution temperatures. The results are as follows ; 1) as the solution temperature increased in IN $\textrm{H}_2\textrm{SO}_4$, the passive current density and critical current density were increased, whereas corrosion potential and break down potential were nearly constant, 2) as the solution temperature increased. the induced time for initiation of crevice corrosion was shortened. 3) The potential range in the crevice was -220mV/SCE to -380mV/SCE according to the distance from the crevice opening, which is lower than that of external surface of -200mV/SCE.

키워드

참고문헌

  1. Corrosion Engineer Mars G. Fontana;Nobert D. Greene
  2. Pitting Corrosion of Merals Z. Szklarska-Smialowska
  3. Principles and prevention of corrosion D.A.Jones
  4. Longman Scientific & Technical(2nd ed.) Corrosion for Science and Engineering K.R.Trechewey;J.Chamberlain
  5. Electrochimica Acta v.46 R.D.Klassen(et al.)
  6. Corrosion Science v.38 J.C.Walton(et al.)
  7. v.15 no.2 F.P.Ijsseling;Br. Corrosion Jr.
  8. v.13 no.1 J.W.Oldfield;W.H.Sutton;Br. Corrosion Jr.
  9. Corrosion. Sci. v.9 N.Stolica
  10. The corrosion science society of korea v.26 no.1 J.B.Lee,Jr.
  11. Korean society of Marine engineers v.27 no.3 S.Y.Baik;E.Y.Na
  12. Basic Reaction Kinetics and Mechanisms H.E.Avery
  13. J. Amer. Chem. Soc. v.60 J.P.Clay;A.W.Thomas
  14. Advances in localized corrosion A.Valdes;H.W.Pickering;H.S.Isaacs(ed.);U.Bertocci(ed.);J.Ruger(ed.);S.Smialowska(ed.)