Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Synthesis and Characteristics of New Poly(p-phenylenevinylene) with Bulky t-Octylphenoxy Group

  • Kim, Yun-Hi (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Hyun-Ouk (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Jung, Sung-Ouk (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Kwon, Soon-Ki (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University)
  • Published : 2003.06.01
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Abstract

A new 2,5-di(t-octylphenoxy) group substituted poly(p-phenylenevinylene) derivative was synthesized by Gilch polymerization. The obtained polymer was characterized by NMR, FT-IR, and chemical analysis and completely soluble in common organic solvents. The polymer showed good thermal stability with T$_{g}$ of 105$^{\circ}C$. The polymer dissolved in chloroform showed maximum emission at 514 nm with a shoulder peak at around 560 nm. The EL spectrum of the ITO/PEDOT/TOP-PPV/Al device was observed maximum emission at 545 nm with a shoulder peak at around 585 nm.m.

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References

  1. Nature v.347 J. H. Burroughes;D. D. C. Bradley;A. R. Brown;R. N. Marks;K. MacKay;R. h. Friend;P. L. Burn;A. B. Holmes
  2. Nature v.357 G. Gustafsson;Y. Cao;G. M. Treacy;F. Klavetter;N. Colaneri;A. J. Heeger
  3. Nature v.365 N. C. Greenham;S. C. Moratti;D. D. C. Bradley;R. H. Friend;P. L. Burn;A. B. Holmes
  4. Nature v.356 P. L. Burn;A. B. Holmes;A. Kraft;D. D. C. Bradley;A. R. Brown;R. H. Friend;R. W. Gymer
  5. Adv. Mater. v.8 J. Bettenhausen;P. Strohriegl
  6. Macromolecules v.34 B. K. An;Y. H. Kim;D. C. Shin;S. Y. Park;H. S. Yu;S. K. Kwon
  7. Jpn. J. Appl. Phys. v.35 M. Yoshida;A. Fujii;Y. Ohmori;K. Yoshino
  8. Nature v.397 R. H. Friend;R. W. Gymer;A. B. Holmes;J. H. Burroughes;R. N. Marks;C. Taliani;D. D. C. Bradley;D. A. Dos Santos;J. L. Bredas;M. Logdlund;W. R. Salaneck
  9. Chem. Phys. Lett. v.369 N. C. Greenham;I. D. W. Samuel;G. R. Hayes;R. T. Phillips;Y. Kessener;S. C. Moratti;A. B. Homes;R. H. Friend
  10. Chem. Mater. v.11 B. Winkler;L. Dai;A. W. H. Mau
  11. Synth. Met. v.76 I. D. W. Samuel;G. Rumbles;C. j. Colison;B. Crystall;S. C. Moratti;A. B. Holems
  12. Polym. Prepr. v.38 D. H. Hwang;S. T. Kim;X. C. Li;B. S. Chuah;J. C. Demello;R. H. Friend;S. C. Moratti;A. B. Holmes
  13. Macromolecules v.32 Z. Pheng;J. Zhang;B. Xu
  14. J. Am. Chem. Soc. v.120 B. R. Hsieh;Y. Yu;E. W. Forsythe;G. M. Schaaf;W. A. Feld
  15. Macromolecules D. C. Shin;Y. H. Kim;H. You;S. K. Kwon
  16. Macromolecules, submitted D. C. Shin;Y. H. Kim;H. You;S. K. Kwon
  17. IEEE Trans. Electron Decices v.44 L. J. Rothberg;M. Yan;E. W. Kwock;T. M. Miller;ME. Galvin;S. Son;F. Papadimitrakopoulos
  18. Science v.265 S. A. Jenekhe;J. A. Osaheni
  19. J. Chem. Soc. Chem. Commun. v.23 D. H. Hwang;H. K. Shim;J. I. Lee
  20. Bull. Korean Chem. Soc. v.23 N. P. H. Nam;V. Parasad;S. W. Cha;D. W. Lee;J.-I. Jin