Macromolecular Research

  • 제11권3호
  • /
  • Pages.194-197
  • /
  • 2003
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  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Synthesis and Characteristics of New Poly(p-phenylenevinylene) with Bulky t-Octylphenoxy Group

  • Kim, Yun-Hi (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Lee, Hyun-Ouk (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Jung, Sung-Ouk (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University) ;
  • Kwon, Soon-Ki (Department of Polymer Science & Engineering and Engineering Research Institute, Gyeongsang National University)
  • 발행 : 2003.06.01
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초록

A new 2,5-di(t-octylphenoxy) group substituted poly(p-phenylenevinylene) derivative was synthesized by Gilch polymerization. The obtained polymer was characterized by NMR, FT-IR, and chemical analysis and completely soluble in common organic solvents. The polymer showed good thermal stability with T$_{g}$ of 105$^{\circ}C$. The polymer dissolved in chloroform showed maximum emission at 514 nm with a shoulder peak at around 560 nm. The EL spectrum of the ITO/PEDOT/TOP-PPV/Al device was observed maximum emission at 545 nm with a shoulder peak at around 585 nm.m.

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