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The Ion Effect on Dewaterability of Alumina-Metal EDTA System

  • Published : 2003.05.01

Abstract

The specific ion effects are observed in the alumina-metal EDTA(Ethylene Diamine Tetraacetic Acid) system. These effects seem to be associated with the fluidity of the metal ion in the complex. A consideration of the order of adsorption of the complexes on alumina indicates that a specific ion effect also affects the stability of the system. It is clear that EDTA and its heavy metal complexes have a significant effect on the dewaterability of alumina. These effects are not well represented by zeta potential measurements, especially for EDTA alone. With the nonspeciating complexes, though, the maximum permeability is predicted by the pH$\_$zpc/ from zeta potential measurements. At other pH value, the refiltration rate is better predicted by the state of coagulation as measured by log W.

Keywords

References

  1. J. Colloid Interface Sci. v.56 no.1 The Problem of Dewatering Clay Slurries : Factors Controlling Filterability Wright,H.J.L.;J.A.Kitchener https://doi.org/10.1016/0021-9797(76)90146-6
  2. J. Coll. Sci. v.23 Flocculation, Subsidence and Filtration of Phosphate Slimes Smellie,R.H.;V.K.LaMer
  3. J. Phys. Chem. v.66 The Adsorption-Flocculation Reactions of a Polymer with an Aqueous Colloidal Dispersion Healy,T.W.;V.K.LaMer https://doi.org/10.1021/j100816a014
  4. Chemical Engineering Progress v.49 no.6 Resistance and Compressibility of Filter Cakes Grace,H.P.
  5. Proceed. AWWA Seminar on Coagulation and Filtration Filtration-Back to the Basics Cleasby,J.L.
  6. J. Phys. Chem. v.63 The Effect of Solid Content on the Adsorption and Flocculation Behavior of Silica Suspension Kane,J.C.;V.K.LaMer;H.B.Linford
  7. Nato. Advd. Study Insts. Ser. 2, The Scientific Basis of Filtration Permeability of Filter media Leclerc,D.
  8. J. Chem. Soc. Faraday Trans. I v.69 Low Angle Light Scattering Technique for Study of Coagulation Lips,A.;E.Willis https://doi.org/10.1039/f19736901226
  9. J. Colloid Interface Sci. v.43 no.2 Specific Adsorption of Cations on Hydrous γ-A1203 Huang,C.P.;W.Stumm https://doi.org/10.1016/0021-9797(73)90387-1
  10. Chem. Rev. v.41 The Electrical Double Layer and Theory of Electrocapillarity Grahame,D.C. https://doi.org/10.1021/cr60130a002
  11. Faraday Discuss. Chem. Soc. v.52 Theory of the Differential Capacity of the Oxide/Aqueous Electrolyte Interface Levine,S.;A.L.Smith https://doi.org/10.1039/df9715200290
  12. J. Electroanal. Chem. v.13 The Discrete-Ion Effect in Ionic Double-Layer Theory Levine,S.;J.Mingins;G.M.Bell https://doi.org/10.1016/0022-0728(67)80125-6