Journal of the Korean Ceramic Society (한국세라믹학회지)

The Korean Ceramic Society (한국세라믹학회)
권호 표지
DOI QR코드

DOI QR Code

Microwave Dielectric Properties of (Pb0.4Ca0.6)[(Fe1/2Nb1/2)1-x(Mg1/3Nb2/3)x]O3 Ceramics

  • Kim, Eung-Soo (Department of materials Engineering, Kyonggi University) ;
  • Han, Ki-Moon (MLCC Research Group, Samaung Electro Mechanics Co.) ;
  • Kim, Jong-Hee (Department of Ceramic Engineering, Yonsei University) ;
  • Yoon, Ki-Hyun (Department of materials Engineering, Kyonggi University)
  • Published : 2003.04.01
Download PDF
⟨ Previous Next ⟩

Abstract

Microwave dielectric properties of (P $b_{0.4}$C $a_{0.6}$)[($Fe_{\frac{1}{2}}$N $b_{\frac{1}{2}}$)$_{1-x}$ (M $g_{1}$ 3/N $b_{2}$ 3/)x] $O_3$ (PCFMN) ceramics were investigated as a function of (M $g_{1}$ 3/N $b_{2}$ 3/)$^{4+}$ content (0.1$\leq$x$\leq$0.8). A single perovskite phase with the cubic structure was obtained through the given composition range. The unit cell volume was increased with (M $g_{1}$ 3/N $b_{2}$ 3/)$^{4+}$, due to the larger average ionic size of (M $g_{1}$ 3/N $b_{2}$ 3/)$^{4+}$ than that of ($Fe_{\frac{1}{2}}$N $b_{\frac{1}{2}}$)$^{4+}$ for B-site ion. Dielectric constant (K) and Temperature Coefficient of Resonant Frequency(TCF) of PCFMN ceramics were dependent on (M $g_{1}$ 3/N $b_{2}$ 3/)$^{4+}$ content due to the decrease of ionic polarizability and B-site bond valence, respectively. Qf value was decreased with (M $g_{1}$ 3/N $b_{2}$ 3/)$^{4+}$ content due to the decrease of grain size. Typically, K of 73.56, Qf of 5,074 GHz and TCF of -6.45 ppm/$^{\circ}C$ were obtained for the specimens with x=0.4 sintered at 125$0^{\circ}C$ for 3 h.125$0^{\circ}C$ for 3 h.

Keywords

References

  1. Jpn. J. Appl. Phys v.31 Dielectric Properties of(Pb,Ca) (Me,Nb)O at Microwave Frequencies J.Kato;H.Kagata;K.Nishimoto
  2. Jpn. J. Appl. Phys. v.32 no.9B Dielectic Properties of Pb-based perovskite Substituted by Ti for B-site at Microwave Frequencies H.Kagata;J.Kato;K.Nishimoto;T.Inoue https://doi.org/10.1143/JJAP.32.4332
  3. Jpn. J. Appl. Phys. v.32 no.9B Low-temperature-fireable Dielectric Material Pb(Fe₂₃W₁₃ )O₃ (Pb,Ca)(Fe₁₂ Nb₁₂ )O₃ for Microwave Use M.Nakano;K.Suzuki;T.Miura;M.Kobayashi https://doi.org/10.1143/JJAP.32.4314
  4. J. Am. Ceram. Soc. v.84 no.1 Relationship between the Bond Valence and the Temperature Coefficient of the Resonant Frequency int th Complex Pervskite H.S.Park;K.H.Yoon;E.S.Kim https://doi.org/10.1111/j.1151-2916.2001.tb00614.x
  5. Mater. Chem. Phys. v.79 Effect of Bond Valence on Microwave Dielectric Properties of Complex Perovskite Ceramics H.S.Park;K.H.Yoon;E.S.Kim https://doi.org/10.1016/S0254-0584(02)00266-3
  6. Acta Cryst v.A32 Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides R.D.Shannon
  7. J. Mater. Res. v.12 no.10 Processing and Characterization of Lead Magnesium Tantalate Ceramics M.A.Akabas;P.K.Davies https://doi.org/10.1557/JMR.1997.0348
  8. Rev. Sci. Instrum. v.6 Percision Lattice Constants from X-ray Powder Photographs M.U.Cohen https://doi.org/10.1063/1.1751937
  9. ASTM C 373-72 Water Absorption, Bulk Density, Apparent Porosity and Apparent Specific Gravity of Fired Whiteware Products
  10. IRE Trans. Microwave Theory Tech. v.8 A Dielectric Method of Measuring Inductive Capacitance in the Millimeter Range B.W.Hakki;P.D.Coleman https://doi.org/10.1109/TMTT.1960.1124749
  11. IEEE MTT-S Digest. Precise Measurement Method for Temperature Coefficient of Microwave Dieletric Resonator Material T.Nishikawa;K.Wakino;H.Tanaka;Y.Ishikawa
  12. Acta. Cryst. v.B41 Bond-valence Parameters Obtained from a Systematic Analysis of the Inorganic Crystal Structure Data-base I.D.Brown;D.Altermatt
  13. J. Appl. Phys. v.73 no.1 Dielectric Polarizabilities of Ions in Oxides and Fluorides R.D.Shannon https://doi.org/10.1063/1.353856
  14. J. Am. Ceran. Soc. v.82 no.8 Effects of Sm Substitution on Dielectric Properties of Ca Sm TiO Ceramics at Microwave Frequencies W.S.Kim;E.S.Kim;K.Y.Yoon
  15. J. am. Ceram. Soc. v.74 Chemical Processing and Microwave Characteristics of (Zr,Sn)TiO₃ Microwave Dielectricies S.Hirano;T.Hayashi;A.Hattori https://doi.org/10.1111/j.1151-2916.1991.tb04105.x
  16. J. Mater. Sci. v.27 Microwave Properties of ZrO ­TiO₂­SnO₂Ceramics D.N.Iddles;A.J.Bell;A.J.Moulson https://doi.org/10.1007/BF00576276

Cited by

  1. Dielectric properties of Sn-substituted lead calcium iron niobate vol.27, pp.4, 2016, https://doi.org/10.1007/s10854-015-4204-8