Influence of DCS Post flow on the Properties of $\textrm{WSi}_{x}$ Thin films

DCS Post Flow가 $\textrm{WSi}_{x}$ 박막 특성에 미치는 영향

  • Published : 2003.04.01

Abstract

In this paper, we studied the physical and electrical characteristics of $\textrm{WSi}_{x}$ thin film with respect to the adoption of the DCS (dichlorosiliane) post flow and the variation of deposition temperature. XRD measurements show that as deposited thin film has a hexagonal structure regardless of deposition Process. However, we find that the phase of thin film has changed to a tetragonal structure after the heat treatment at $680^{\circ}C$. Adoption of DCS post flow and increment of deposition temperature result in the increments of Si/W composition ratio. These conditions also result in the increment of sheet resistance by the amount 3.0~4.2$\Omega$/$\square$, but give the tendency in the decrement of stress by 0.27~0.3 E10dyne/$\textrm{cm}^2$. We also find that the contact resistance of word line and bit line interconnection was decreased by the amount 5.33~16.43$\mu$$\Omega$-$\textrm{cm}^2$, when applying DCS post flow and increasing deposition temperature.

Keywords

References

  1. K. Roh, S. Youn, S. Yang and Y. Roh, 'Tungsten silicide for the alternate gate metal in metal-oxide semiconductor device', J. Vac. Sci. Technol. A 19(4), Jul/Aug pp. 1562-1565, 2001 https://doi.org/10.1116/1.1345914
  2. S. F. Lin, C. H. On, S. Lee, Y. C. Tien, and C. F. Hsu, 'Investigation of the time-delay effect on the critical dimension of tungsten silicide/polysilicon gate after reactive ion etching', Proceedings of the International Symp. Plasma Etching Processes for Sub-Quarter Micron Devices, pp. 186-192, 1999
  3. S. Abudi, D. Hannoun, K. Kitt, C. Garcia, and J. Pearse, 'Tungsten and Tungsten Silicide$(WSi_x)$ as Gate Materials for Trench MOSFEF's', Proceedings of the 12th International Symp. on Power Semiconductor Device and IC's, pp. 181-184, 2000
  4. J. S. Byun, B. H. Lee, J. S. Park, D. K. Sohn, S. J. Choi, and J. J. Kim, 'Formation of high Conductivity $WSi_x$ Layer and its Characterization as a gate Electrode', J. Electrochem. Soc., Vol. 145, No. 9, pp. 3228-3235, 1998 https://doi.org/10.1149/1.1838790
  5. J. G. Lee, S. H. Oh, J. M. Lee, E. G. Lee, I. G. Lim, W. K. Park, and G. H. Kim, 'High temperature cracking of tungsten polycide films on quartz sunstrate', Thin Solid Films, Vol. 370, No. 1-2, pp. 307-310, 2000 https://doi.org/10.1016/S0040-6090(00)00936-6
  6. M. Godbole, 'Silicon to Tungsten Ratio Determination Tungsten Silicide using XRF', Proceeding of the Biennial Unversity / Govenment / Industry Microelectron Symp., pp. 46-50, 2001 https://doi.org/10.1109/UGIM.2001.960292
  7. H. S. Kim, I. S. Yeo, S. M. Lee, S. D. Lee, and S. K Lee, 'Oxidation behavior of Nitrogen Implanted Dichlorosilane-based W-polycide Gate', J. Electrochem. Soc., Vol. 146, No. 12, pp. 4630-4633, 1999 https://doi.org/10.1149/1.1392685
  8. J. S. Byun, B. H. Lee, J. S. Park, D. K. Sohn, J. G. Hong, W. J. Cho, S. J. Choi, and J. J. Kim, 'Reduction of Dichlorosiliane-Based Tungsten Silicide Resistivity by Amorphization and its Appilicability as an Electrode', J. Electrochem. Soc., Vol. 146, No. 6, pp. 2261-2269, 1999 https://doi.org/10.1149/1.1391925
  9. S. Santucci, L. Lozzi, M. Passacantando, and P. Picozzi, 'Studies on structural, electrical, compositional, and mechanical properties of $WSi_x$ thin films produced by low-pressure chemical vapor deposition', J. Vac. Sci. Technol. A 16(3), pp. 1207-1212, 1998 https://doi.org/10.1116/1.581260
  10. C. A. Bradbury and D. K. Fillmore, 'Tungsten silicide composition analysis by Rutherford backscattering spectroscopy, Auger electron spectroscopy, and x-ray photoelectron spectroscopy', J. Vac. Sci. Technol. A 16(3), pp. 1103-1105, 1998 https://doi.org/10.1116/1.581240
  11. J. Y. Adachi, B. C. McIntosh and D. E. Badt, 'Integrated tungsten polycide : analysis of interface composition', Thin Solid Films, Vol. 320, pp. 128-133, 1998 https://doi.org/10.1016/S0040-6090(97)01071-7
  12. J. S. Byun, B. H. Lee, J. S. Park and J. J. Kim, 'Characterization of the Dopant Effect on Dichlorosilane-Based Tungsten Silicide Deposition', J. Electrochem. Soc., Vol. 144, No. 10, pp. 3572-3582, 1997 https://doi.org/10.1149/1.1838050