Macromolecular Research

  • 제11권4호
  • /
  • Pages.250-255
  • /
  • 2003
  • /
  • 1598-5032(pISSN)
  • /
  • 2092-7673(eISSN)
한국고분자학회 (The Polymer Society of Korea)
권호 표지

Effect of the Photosensitizer on the Photo refractive Effect Using a Low $T_g$ Sol-Gel Glass

  • Choi, Dong-Hoon (College of Environment and Applied Chemistry, Institute of Natural Sciences, Kyung Hee University) ;
  • Jun, Woong-Gi (College of Environment and Applied Chemistry, Institute of Natural Sciences, Kyung Hee University) ;
  • Oh, Kwang-Yong (College of Environment and Applied Chemistry, Institute of Natural Sciences, Kyung Hee University) ;
  • Yoon, Han-Na (College of Environment and Applied Chemistry, Institute of Natural Sciences, Kyung Hee University) ;
  • Kim, Jae-Hong (College of Environment and Applied Chemistry, Institute of Natural Sciences, Kyung Hee University)
  • 발행 : 2003.08.31
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

We prepared the photorefractive sol-gel glass based on organic-inorganic hybrid materials containing a charge transporting molecule, second-order nonlinear optical (NLO) chromophore, photosensitizer, and plasticizer. Carbazole and 2-{ 4-[(2-hydroxy-ethyl)-methyl-amino]-benzylidene}-malononitrile were reacted with isocyanato-triethoxy silane and the functionalized silanes were employed to fabricate the efficient photorefractive media induding 2,4,7-trinitrot1uorenone (TNF) to form a charge transfer complex. The prepared sol-gel glass samples showed a large net gain coefficient and high diffraction efficiency at a certain composition. As the concentration of photosensitizer increased, the photorefractive properties were enhanced due to an increment of charge carrier density. Dynamic behavior of the diffraction efficiency was also investigated with the concentration of the photosensitizer.

키워드

참고문헌

  1. B. L. Volodin, R. Sandalphon, K. Meerholz, B. Kippelen, N. V. Kukhtarev, and N. Peyghaambarian, Opt. Eng., 34. 2213 (1995)
  2. C. J. Chang, W. T. Whang. C. C. Hsu, Z. Y. Ding. K. Y. Hsu, and S. H. Lin. Macromolecules, 32, 5637 (1999)
  3. S. J. Strutz and L. M. Hayden, Appl. Phys. Lett., 74. 2749 (1999)
  4. A. Goonesekera, D. Wright. and W. E. Moerner, Appl. Phys. Lett., 76, 3358 (2000)
  5. D. V. Steenwinckel, C. Engels. E. Gubbelmans, E. Hendrickx, C. Samyn, and A. Persoons, Macromolecules, 33, 4074 (2000)
  6. H. Moon, J. Hwang. N. Kim, and S. Y. Park, Macromolecules. 33, 5116 (2000)
  7. K. Okamoto, T. Nomura, S. H. Park, K. Ogino, and H. Sato, Chem. Mater, 11, 3279 (1999)
  8. M. S. Ho, C. Barrett, J. Paterson, M. Esteghamatian, A. Natansohn, and P. Rochon, Macromolecules, 29, 4613 (1996)
  9. Z. Peng, A. R. Gharavi, and L. Yu. J. Am. Chem. Soc., 119, 4622 (1997)
  10. J. Sohn, J. Hwang, S. Y. Park. J. K. Lee. J. H. Lee. J. S. Chang, G. J. Lee, B. Zhang. and Q. Gong, Appl. Phys. Lett., 77, 1422 (2000)
  11. B. Darracq, F. Chaput, K. Lahlil. J. P. Boilot, Y. Levy, V. Alain, L. Ventelon, and M. B. Desce, Optical Maier, 9, 265 (1998)
  12. G. H Hsiue, W. J. Kuo. C. H. Lin. and R. J. Jeng, Macromol. Chem. Phys., 17, 2336 (2000)
  13. B. Darracq, M. Canva, F. Chaput. J. P. Boilot, D. Riehl. Y. Levy, and A. Brun, AppI. Phys. Lett., 70. 292 (1997)
  14. D. H. Choi, H. T. Hong. W. G. Jun. and K. Y. Oh, Opt. Mater, 21, 373 (2002)
  15. H. Kogelnik, Bell. Syst. Tech. J., 48, 2909 (1969)
  16. H. Ono, T. Kawamura, N. M. Frias, K. Kitamura, N. Kawatsuki, H. Norisada, and T. Yamamoto, J. Appl. Phys., 88, 3853 (2000)
  17. Y. Cui, B. Swedek, N. Cheng, J. Zieba, and P. N. Prasad, J. Appl. Phys., 85, 38 (1999)
  18. S. M. Silence, R. J. Twieg, G. C. Bjorklund, and W. E. Moerner, Phys. Rev. Lett., 73, 2047 (1994)
  19. B. E. Jones. S. Ducharme, M. Liphardt, A. Goonesekera, J. M. Takacs, L. Zhang, and R. Athlaye, J. Opt. Soc. Am. B., 11, 1064 (1994)
  20. S. M. Silence, J. C. Scott, J. J. Stankus, W. E. Moerner, C. R. Moylan, G. C. Bjorklund, and R. J. Tweig, J. Phys. Chem., 99, 4096 (1995)