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Thermal Decomposition of Octanethiolate Self-Assembled Monolayers on Cu(111) in UHV

  • Sung, Myung-M. (Department of Chemistry, Kookmin University) ;
  • Yun, Won-J. (Department of Chemistry, Kookmin University) ;
  • Lee, Sun-S. (Advanced Materials Division, Korea Research Institute of Chemical Technology) ;
  • Kim, Yun-Soo (Advanced Materials Division, Korea Research Institute of Chemical Technology)
  • 발행 : 2003.05.20

초록

Octanethiol ($CH_3(CH_2)_7SH$) based self-assembled monolayer on Cu(111) in ultra-high vacuum has been examined using x-ray photoelectron spectroscopy (XPS), temperature programmed desorption (TPD), intergrated desorption mass spectrometry (IDMS), and contact angle analysis. The results show that the octanethiolate monolayers similar to those on gold are formed on Cu(111). The monolayers are stable up to temperatures of about 480 K. Above 495 K the monolayers decompose via the γ-hydrogen elimination mechanism to yield 1-octene in the gas phase. The thiolate head groups on the copper surface change to Cu₂S following the decomposition of hydrocarbon fragments in the monolayers at about 605 K.

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참고문헌

  1. Ulman, A. An Introduction to Ultrathin Organic Films; AcademicPress: Boston, MA, 1991.
  2. Swalen, J. D.; Allara, D. L.; Andrade, J. D.; Chandross, E. A.;Garoff, S.; Israelachvili, J.; McCarthy, T. J.; Murray, R.; Pease, R.F.; Rabolt, J. F.; Wynne, K. J.; Yu, H. Langmuir 1987, 3, 932. https://doi.org/10.1021/la00078a011
  3. Wasserman, S. R.; Tao, Y.-T.; Whitesides, G. M. Langmuir 1989,5, 1074. https://doi.org/10.1021/la00088a035
  4. Laibinis, P. E.; Whitesides, G. M. J. Am. Chem. Soc. 1992, 114,9022. https://doi.org/10.1021/ja00049a038
  5. Kluth, G. J.; Sung, M. M.; Maboudian, R. Langmuir 1997, 13,3775. https://doi.org/10.1021/la970135r
  6. Sung, M. M.; Kluth, G. J.; Yauw, O. W.; Maboudian, R. Langmuir1997, 13, 6168.
  7. Nishida, N.; Hara, M.; Sasabe, H.; Knoll, W. Jpn. J. Appl. Phys.1996, 35, L799. https://doi.org/10.1143/JJAP.35.L799
  8. Sung, M. M.; Kim, Y. Bull. Korean Chem. Soc. 2001, 22, 748.
  9. Briggs, D.; Seah, M. P. Practical Surface Analysis; John Willy &Sons Ltd.: England, 1990.
  10. Dubois, L. H. Rev. Sci. Instrum. 1989, 60, 410. https://doi.org/10.1063/1.1140392
  11. Neumann, A. W.; Good, R. J. Surface and Colloid Science Vol. II:Experimental Methods; Plenum Press: New York, 1979.
  12. Galtayries, A.; Bonnelle, J.-P. Surf. Interface Anal. 1995, 23, 171. https://doi.org/10.1002/sia.740230308

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  11. Thermal Stability of Thiolate Self-Assembled Monolayers on Copper Surface vol.646, pp.None, 2003, https://doi.org/10.4028/www.scientific.net/amr.646.18
  12. Self-assembled monolayers of thiolates on metals: a review article on sulfur-metal chemistry and surface structures vol.4, pp.53, 2014, https://doi.org/10.1039/c4ra04659e
  13. Growth of Layered Copper-Alkanethiolate Frameworks from Thin Anodic Copper Oxide Films vol.123, pp.28, 2003, https://doi.org/10.1021/acs.jpcc.9b03264
  14. Corrosion inhibitor by a polymerizable columnar mesogen based on hexabenzocoronene derivative vol.67, pp.9, 2003, https://doi.org/10.1002/jccs.202000168