DOI QR코드

DOI QR Code

A Study on Cleaning Process for Benzene Recovery in Activated Carbon Bed

활성탄을 충전한 흡착탑에서 벤젠 회수를 위한 세정공정의 연구

  • Kang, Sung-Won (Department of Chemical Engineering, Hongik University) ;
  • Min, Byong-Hoon (Department of Chemical Engineering, Suwon University) ;
  • Suh, Sung-Sup (Department of Chemical Engineering, Hongik University)
  • 강성원 (홍익대학교 공과대학 화학공학과) ;
  • 민병훈 (수원대학교 공과대학 화학공학과) ;
  • 서성섭 (홍익대학교 공과대학 화학공학과)
  • Published : 2002.06.30

Abstract

Experimental Study was carried out for benzene desorption by purge gas or evacuation in an activated carbon bed. As purge gas flow rate increased, desorption rate increased due to the higher interstitial linear gas velocity. For various purge gas flow rates, desoption curves almost got together if they were plotted against dimensionless time. At a higher flow rate, mass transfer zone became narrower. Temperature drop in the bed was more fast and severe at higher flow rates and higher outer temperature. It was found out that desorption was almost completed when the temperature in the drop of the bed returned to the initial temperature before temperature drop. Desorption by vacuum purge was completed in shorter time than desorption by purge gas. Countercurrent purge was more effective than cocurrent purge.

Keywords

References

  1. 한화진, '선진국의 VOC 규제 및 관리동향', 첨단환경기술, 7, June, 2 (1997)
  2. 한화진, '국내 VOC현황 및 배출원별 관리방향', 첨단환경기술, 6, July, l (1996)
  3. 박철진, 'VOC의 발생 현황 및 안전보건환경에 미치는 영향', 한국산업안전공단, 안연98-17-248, 33-85 (1998)
  4. S. W. Kang, B. H. Min, and S. S. Suh, 'Breakthrough Behavior of Benzene and Toluene in Adsorption Bed', J. Kor. Oil Chem. Soc., 17, June, 83 (2000)
  5. H. S. Kim and Y. S. Paik, 'Adsorption Charactehsdcs of Volatile Organic Compounds - BTX on Activated Carbon Fiber', J. Kor. Soc. Atmospheric Environment, 15, 805 (1999)
  6. J. D. Seader and E. J. Henley, 'Separation Process Phnciples', 820-823, WiIey, New York (1998)
  7. J. H. Yun and D. K. Choi, 'Equilibha and Dynamics for Mixed Vapors of BTX in an Activated Carbon Bed', AIChE J., 45, 751 (1999) https://doi.org/10.1002/aic.690450410
  8. J. H. Kim, C. W. Seong, H. Y. Park, C. H. Lee, and W. S. Kim, 'Adsorption of Volatile Organic Compounds in Fixed Bed Packed with Activated Carbon Fibers', Theories Appl. Chem. Eng., 3, 373 (1997)
  9. J. H. Yun and D. K. Choi, 'Adsorption Equilibria of Chlohnated Organic Solvents onto Activated Carbon', Ind. Eng. Chem.Res., 37, 142 (1998)
  10. R. T. Yang, 'Gas Separation by Adsorption Processes' p.93, Butterworth, New York (1987)
  11. 이규성 외, '대기오염 제어공학', p. 415, 형설출판사, 서울 (2000)
  12. H. S. Shin, Y. S. Kim, and K. S. Huh, 'Measurements of Indoor and Outdoor Volatile Organic Compounds(VOCs) Concentrations in Ambient Air', J. Kor. 5oc Atmospheric Envirorvnent, 9, 310 (1993)
  13. K. S. Hwang, D. K. Choi, and S. Y. Gong, 'The Thermal Regeneration Charateristics of Volitile Organic Compounds on an Activated Carbon Bed(I):Adsorption Step', J. of KICbE, 36, April, 159 (1998)
  14. D. J. Kim, W. G. Shim, and H. A. Moon,'Adsorption Equilibrium of Solvent Vapors on Activated Carbons', Kor. J. Chem. Ene., 18, 518 (2001) https://doi.org/10.1007/BF02698300
  15. K. S. Na, Y. P. Kim, K. J. Moon, S. 0. Baek, S. M. Hwang, and S. R. Kim, 'Compahson of Sampling and Analysis Methods for Volatile Organic Compounds in Ambient Air', J. Kor. Soc Atmospheric Erwironment, 14, 507 (1998)