DOI QR코드

DOI QR Code

($H_{2}S$ Adsorption Capacity of $Na_{2}CO_{3}$ and $KIO_{3}$ Impregnated Activated Carbon

($Na_{2}CO_{3}$$KIO_{3}$ 첨착 왕겨활성탄의 $H_{2}S$ 흡착특성

  • Kim, Jun-Suk (Department of Chemical Engineering, Myongji University) ;
  • Kim, Myung-Soo (Department of Chemical Engineering, Myongji University)
  • 김준석 (명지대학교 공과대학 화학공학과) ;
  • 김명수 (명지대학교 공과대학 화학공학과)
  • Published : 2002.09.30

Abstract

Activated carbons with high surface area of 2,600 $m^{2}/g$ and high pore volume of 1.2 cc/g could be prepared by KOH activation of rice hulls at a KOH:char ratio of 4:1 and $850^{\circ}C$. In order to increase the adsorption capacity of hydrogen sulfide, which is one of the major malodorous component in the waste water treatment process, various contents of $Na_{2}CO_{3}$ and $KIO_{3}$ were impregnated to the rice-hull activated carbon. The impregnated activated carbon with 5 wt.% of $Na_{2}CO_{3}$ showed improved $H_{2}S$ adsorption capacity of 75 mg/g which is twice of that for the activated carbon without impregnation and the impregnated activated carbon with 2.4 wt.% of $KIO_{3}$ showed even higher $H_{2}S$ adsorption capacity of 97 mg/g. The improvement of $H_{2}S$ adsorption capacity by the introduction of those chemicals could be due to the $H_{2}S$ oxidation and chemical reaction with impregnated materials in addition to the physical adsorption of activated carbon.

Keywords

References

  1. 정회성, 이송호, '환경기초시설 설치 ·운영 업무의 정부간 분담 방향', 한국환경기술개발원 연구보고서, 서울 (1995)
  2. F. Adib, A. Bagreev, and T. J. Bandosz, Interface Sci. 214, 407 (1999)
  3. G. I. Park, H. K. Lee, Y. T. Park, and H. Moon, J. of KSEE, 19(9), 1125 (1997)
  4. 오승배, '인산($H_3PO_4$) 첨착촬성탄에 의한 암모니아 가스 흡착효과', 층북대학교 석사 학위 논문 (1996)
  5. 한국화학연구소, '첨착활성탄소의 제조와 활용에 관한 연구(II)', 과학기술처, 서울 (1988)
  6. 박성 원, '트리에칠렌디아민-첨착활성탄에 의한 메칠아요다이드의 흡 · 탈착 특성 연구', 한국과학기술원 박사학위논문, 대전 (1994)
  7. K. Gergova and S. Eser, Carbon, 34(7), 879 (1996) https://doi.org/10.1016/0008-6223(96)00028-0
  8. 김명수, 흥종철, 화학공학회, 36(6), 913 (1998)
  9. 흥종철, '왕겨로부터 고비표면적의 활성탄 제조 및 흠착특성', 명지대학교 석사학위논문 (1998)
  10. A. A. Malik, P. R. Meddings, A. Patel, and K. M. Thomas, Carbon, 34(4), 439 (1996) https://doi.org/10.1016/0008-6223(95)00165-4
  11. S. Lowell and J. E. Shields, 'Powder Surface Area and Porosity', 3rd ed. Chapman & Hall (1991)
  12. K. H. Kim and C. S. Shin, Carbon, 2(2), 109 (2001)
  13. C. N. Satterfield, 'Heterogeneous Catalysis in Industrial Practice', 2nd ed., McGraw-Hill, Singapore (1991)
  14. A. Bagreev and T. J. Bandosz, Ind Eng. Chem. Res. 41, 672 (2002) https://doi.org/10.1021/ie010599r
  15. A. Bagreev, H. Rahman, and T. J.Bandosz, Environ. Sci. Technot, 34, 4587(2000) https://doi.org/10.1021/es001150c
  16. 심재온, 고경열, 김선영, 양범호, 유승곤, 화학공학의 이론과 응용, 3, 2097 (1997)
  17. M. P. Cal, B. W. Strickler, and A. A. Lizzio, Carbon, 38, 1757 (2000) https://doi.org/10.1016/S0008-6223(00)00010-5
  18. J. Masuda, J. Fukuyama, and S. Fujh, Chemosphere, 39(10), 1611-1616 (1999) https://doi.org/10.1016/S0045-6535(99)00059-4
  19. 조기철, '$Na_2CO_3$ 첨착활성탄을 이웅한 $H_2$S제거에 관한 연구', 부산대학교 석사학위논문 (1999)