하수슬러지 중 Nonylphenol, Octylphenol, Di (2-ethylhexyl)phthalate 의 연구

A Study on Nonylphenol, Octylphenol, and Di (2-ethylhexyl)phthalate in Sewage Sludge

  • 김종훈 (전주대학교 자연과학부 환경과학전공)
  • Kim, Jong-Hun (Dept. of Environ. Eng. & Sci. Jeonju University)
  • 투고 : 2002.02.05
  • 발행 : 2002.10.25

초록

전국적으로 67 개소의 하수종말처리장에서 배출되는 하수슬러지 중 nonylphenol (NP), octylphenol (OP), di (2-ethylhexyl)phthalate (DEHP)를 이염화메탄용액으로 Soxhlet 추출후 GC/MS-SIM방법으로 분석하였다. 대부분의 하수슬러지에서 NP와 DEHP가 검출되었으며 OP는 검출되지 않았다. NP의 범위와 평균 농도는 각각 nd~593, $62{\mu}g/g$ dry 였고, DEHP의 범위와 평균농도는 각각 13~4773, $1176{\mu}g/g$ dry이었다. NP에 비하여 DEHP가 20 배 이상 높게 포함되어있었다. NP와 DEHP의 지역별 농도 증가는 전라남북도 (제주도) < 충청남북도 (강원도) < 경상남북도 < 광역시 < 경기도 순으로 증가하였다.

Determination were performed for the presence of three common environmental endocrine disrupting compounds (EDC), namely nonylphenol (NP), octylphenol (OP), di (2-ethylhexyl)phthalate in sewage sludge from 67 wastes plants, using Soxhlet extraction and GC/MS-SIM. NP and DEHP were detected in almost every sludges but OP was not detected. The range and mean value for NP of all sludge samples were nd~593, $62{\mu}g/g$ dry and the two statistic values for DEHP of those were 13~4733, $1176{\mu}g/g$ dry respectively. DEHP content was 20 times greater than NP in sludges. Concentrations of NP and DEHP in sludge from individual area were increased as following order ; Jeolla South and North Province (Cheju) < Chungcheong South and North Province (Kwangwon) < Gyungsang South and North Province < Wide City < Kyunggi Province.

키워드

과제정보

연구 과제 주관 기관 : 전주대학교

참고문헌

  1. 환경관리연구소,“하수슬러지 관리 및 재활용방안', 첨단환경기술 (2000,11)
  2. L. H. Keith, “Environmental endocrine disruptors, A Hand book of property data', John Wiley & Sons, New york, p. 4 (1997).
  3. S. R. Wild, K. S. Waterhouse, S. P. McGrath, and K. C. Jones, Environ. Sci. & Technol, 24, 1706 (1990).
  4. S. R. Wild, J. P. Obbard, C. I. Munn, M. L. Berrow a nd K. C. Jones, The Science of the Total Environment, 101, 235 (1991).
  5. A. L. Page, T. G. Logan, and J. A. Ryan 'Land applic ation of sludge'. Lewis Publisher Inc. Michigan. USA., p. 21 (1987).
  6. S. R. Wild and K. C. Jones, Environmental Pollution. 88, 91 (1995).
  7. S. R. Wild and K. C. Jones, Environmental Toxicology and Chemistry, 12, 5 (1993).
  8. N. T. Edwards, J. Environ. Qual., 12, 427 (1983).
  9. S. R. Wild, M. L. Berrow, S. P. McGrath and K. C. Jones, Environmental Pollution, 76, 25 (1992).
  10. S. R. Wild and K. C. Jones, Water Manegement & Research, 12, 49 (1994).
  11. S. L. Simonich & R A. Hites, Nature, 370 (7), 50 (1994).
  12. S. K. Lotfabad, M. A. Pickard, and M. R. Gray, Environ. Sci. Technol. 30, 1145 (1992).
  13. S. R. Wild and K. C. Jones, J. Environ. Qual., 21, 217 (1992).
  14. G. Sposito, L. J. Lund, and A. S. Chang, Soil Sci. Soc. Am. J., 46, 260 (1982).
  15. S. H. Yoo, J. Y. Lee and K. H. Kim, J. Kor. Soc. Soil Sci. Fert., 28 (3), 207 (1995).
  16. 최희선, 김태진, 분석과학 12 (4), 318 (1999).
  17. 김종훈, 분석과학, 12 (3), 248 (1999).
  18. 김종훈, 분석과학, 13 (3), 357 (2000).
  19. Environmental News Data Service (ENDS) Report No.2 57, 5 (1996).
  20. J. A. Ticker, T. Schettler, T. Guidotti, M. MaCally. and M. Rossi, Amer. J. of Indus. Medicine, 39, 100 (2001).
  21. G. Latini, Biology of the Neonate, 78, 269 (2000).
  22. S. Jobling, Pure & Appl Chem., 70 (9), 1805 (1998).
  23. A. Eschenbach, M. Kastner, R. Bierl, G. Schaefer and B. Mahro, Chemosphere, 28, 683 (1994).
  24. G. Sim, 'Determination of EDC in some biological matrices : development of analytical methodology', BSc, Robert Gorden University, UK, p.27 (2000).
  25. Environmental News Data Service (ENDS) Report No.2 99, 45 (1999).
  26. D. T. Bennie, C. A. Sullivan, H. B. Lee, T. E. Peart, and R. J. Maguire, The Science of the Total Environm ent, 193, 263 (1997).
  27. M. Ahel and W. Giger, Anal. Chem., 57, 1577 (1985).
  28. H. R. Roger, 'Organic contaminants in sewage sludge (EC 9322SLD)', WRc Environment, Medmenham La boratory, Medmenham, p.42-45 (June 1987).
  29. T. J. Wams, The Science of the Total Environment, 66, 1 (1987)