Macromolecular Research

The Polymer Society of Korea (한국고분자학회)
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Conducting Behavior of Carbosilane Dendrimers Including Palladium Ions

  • Kim, Chungkyun (Department of Chemistry, Dong-A University) ;
  • Koo, Bon-Won (Electronic Polymer Lab., Samsung Advanced Institute of Technology) ;
  • Lee, Sang-Bak (Department of Electronics Engineering, Dong-A University) ;
  • Song, Chung-Kun (Department of Electronics Engineering, Dong-A University)
  • Published : 2002.06.01
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Abstract

The conducting behavior of dendritic carbosilanes including palladium ions (Pd$^{2+}$) has been measured. The palladium ion containing dendrimers were prepared by the addition of palladium dichloride to double-layered dendritic carbosilanes, which consist of phenylethynyl groups (-C≡CPh) on the outmost periphery as well as phenylethenyl and propyleneoxy groups (-CH=CPh- and (CH$_2$)$_3$O-) in the inner shell. By measuring conductivities, palladium ion containing dendrimers revealed an increasing tendency according to the increasing number of double bonds in the inner shells of dendritic carbosilanes.s.

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References

  1. Dendritic Molecules Dendritic Molecules G. R. Newkome;C. N. Moorefield;F. Vogtle
  2. Angew. Chem. Int. Ed. v.38 M. Fischer;F. Vogtle https://doi.org/10.1002/(SICI)1521-3773(19990401)38:7<884::AID-ANIE884>3.0.CO;2-K
  3. Chem. Rev. v.99 J.-p. Majoral;A.-M. Caminade https://doi.org/10.1021/cr970414j
  4. J. Am. Chem. Soc. v.121 S. Huang;J. M. Tour
  5. Prog. Polym. Sci. v.25 K. Inoue https://doi.org/10.1016/S0079-6700(00)00011-3
  6. Prog. Polym. Sci. v.25 F. Vogtle;S. Gestermann;R. Hesse;H. Schwierz;B. Windisch https://doi.org/10.1016/S0079-6700(00)00017-4
  7. Acc. Chem. Res. v.34 A. Harada https://doi.org/10.1021/ar000174l
  8. Sensors and Actuator B v.77 B. W. Koo;C. K. Song;C. Kim https://doi.org/10.1016/S0925-4005(01)00750-X
  9. Acc. Chem. Res. v.34 R. M. Crooks;M. Zhao;R. Sun;V. Chechik;L. K. Yeung https://doi.org/10.1021/ar000110a
  10. Synthesis Synthesis C. Kim;A. Kwon
  11. J. Polym. Sci. Polym. Chem. Ed. v.38 C. Kim;M. Ryu https://doi.org/10.1002/(SICI)1099-0518(20000215)38:4<764::AID-POLA12>3.0.CO;2-U
  12. Syn. Met. v.123 C. Kim;E. Park;C. K. Song;B. W. Koo https://doi.org/10.1016/S0379-6779(01)00351-4
  13. Dissertation Dissertation B. W. Koo
  14. J. Organomet. Chem. v.576 S. Cacchi https://doi.org/10.1016/S0022-328X(98)01051-1