Recycling of Biological Industrial Waste as an Adsorbent for Heavy Metals

중금속 제거를 위한 흡착제로서 생물산업 폐기물의 재활용

  • 장재선 (가천길대학 보건행정과) ;
  • 이제만 (인천광역시 보건환경연구원) ;
  • 김용희 (인천광역시 보건환경연구원)
  • Published : 2002.09.01

Abstract

The removal efficiency of heavy metals by chitosan complex isolated from biological industrial waste was investigated through laboratory experiments. The results of the study are as follows. The adsorption kinetics of heavy metals were reached the equilibrium adsorption in approximately 30 minutes and the removal efficiency were showed 70.7~97.4%. The effect of temperature on heavy metals adsorption by chitosan complex shows that as the temperature increased, the amount of heavy metals adsorption per unit weight of chitosan complex increased. The correlation between amount of heavy metals adsorption per unit weight of chitosan complex and temperature were obtained through the coefficient of determination($R^2$). $R^2$ values were 0.75(p<0.05), 0.99(p<0.05) and 0.98(p<0.05) in Hg, Mn, and Zn, respectively. The injected chitosan complex in which 0.1 g was adsorpted highly and the removal of heavy metals was found to have the best removal efficiency A linearized Freundlich equation was used to fit the acquired experimental data. As a result, Freundlich constants, the adsorption intensity(I/n) was 0.5564, 0.4074, 0.5244 on the Hg, Mn, Zn, respectively And the measure of adsorption(k) was 2.2144, 1.6963, 2.0792 on the Hg, Mn, Zn, respectively. So, it was concluded that adsorption of heavy metals by chitosan complex is effective.

Keywords

References

  1. 환경백서 환경부
  2. Health effects of environmental pollutants. George,L.W.
  3. 인천광역시 보건환경연구원보 식품중의 미량 금속에 관한 조사연구 조남규(외)
  4. 산업재해, 직업병 실례와 예방대책 문성명
  5. 환경정책기본법. 법률 4257호 환경부
  6. 수질환경보전법. 법률3889호 환경부
  7. 산업폐수중 중금속처리기술에 관한 연구 과학기술처
  8. 한국폐기물학회지 v.10 no.3 게껍질의 중금숙처리에 관한 연구(Ⅰ) 이성홍;박상옥;박상원
  9. Biotech. Bioeng v.39 Molecular weight dustribution of chitosan isolated from Mucor rouxii under different culture and processing condition. Arcidiacono,S.;Kaplan D.L. https://doi.org/10.1002/bit.260390305
  10. Biotech. Bioeng. v.22 Chelating, film forming and coagulating ability of the chitosan-glucan complex from A. niger indusital wastes Muzzarelli,R.A.A;Tanfani F.;Scarpini G. https://doi.org/10.1002/bit.260220412
  11. 한국환경위생학회지 v.21 no.3 천연고령토의 폐수 중 납 흡착에 관한 연구 이종은
  12. 동화기술 용수 및 폐수처리 양병수
  13. 한양대학교 석사학위논문 국산제올라이트를 이용한 폐수중의 중금속 제거에 관한 연구 김병화
  14. 한국환경위생학회지 v.26 no.1 다진산 점토의 중금속 흡착 특성에 관한 연구 이한영;강안수