Hardness and EDM Processing of MoSi$_2$Intermetallics for High Temperature Ship Engine

고온선박엔진용 MoSi$_2$금속간화합물의 경도와 방전가공특성

  • 윤한기 (동의대학교 기계·정보산업공학부) ;
  • 이상필 (동의대학교 기계·정보산업공학부)
  • Published : 2002.12.01

Abstract

This paper describes the machining characteristics of the MoSi$_2$--based composites through the process of electric discharge drilling with various tubular electrodes. In addition to hardness characteristics, microstructures of Nb/MoSi$_2$laminate composites were evaluated from the variation of fabricating conditions, such as preparation temperature, applied pressure, and pressure holding time. MoSi$_2$-based composites have been developed in new materials for jet engines of supersonic-speed airplanes and gas turbines for high-temperature generators. These high performance engines may require new hard materials with high strength and high temperature-resistance. Also, with the exception of grinding, traditional machining methods are not applicable to these new materials. Electric discharge machining (EDM) is a thermal process that utilizes a spark discharge to melt a conductive material. The tool electrode is almost -unloaded, because there is n direct contact between the tool electrode and the work piece. By combining a non-conducting ceramic with more conducting ceramic, it was possible to raise the electrical conductivity. From experimental results, it was found that the lamination from Nb sheet and MoSi$_2$ powder was an excellent strategy to improve hardness characteristics of monolithic MoSi$_2$. However, interfacial reaction products, like (Nb, Mo)SiO$_2$and Nb$_2$Si$_3$formed at the interface of Nb/MoSi$_2$, and increased with fabricating temperature. MoSi$_2$composites, with which a hole drilling was not possible through the conventional machining process, enhanced the capacity of ED-drilling by adding MbSi$_2$, relative to that of SiC or ZrO$_2$reinforcements.

Keywords

References

  1. 한국정밀공학회, 춘계학술대회논문집 MoSi₂기지 복합재료의 ED-drilling 김창호;윤한기
  2. 한국해양공학회지 v.13 no.4 Nb/MoSi₂적층복합재료의 경도특성에 미치는 제조온도의 영향 이상필;윤한기
  3. 한국해양공학괴 춘계학술대회 강연 논문집 Nb/MoSi₂적층복합재료의 제조온도에 의한 경도특성 평가 이상필;윤한기
  4. Metall. Mater. Trans. v.26A The effect of niobium morphology on the facture behavior of MoSi2/Nb composites Alman, D.E.;Stoloff, N.S.
  5. Metall. Mater. Trans. v.27A Fracture and fatigue crack growth behavior in ductile-phase toughening molybdenum disilicide: effect of niobium wire vs particulate reinforcements Badrinarayanan, K.;Mckelvey, A.L.;Venkateswara Rao, K.T.;Ritchie, R.O.
  6. Acta Metall. Mater. v.38 Ductile reinforcement toughening of γ-TiAl: effects of debonding and ductility Dave, H.E.;Evans, A.G.;Odette, G.R.;Mehrabian, R.;Emiliani, M.L.;Hecht, R.J. https://doi.org/10.1016/0956-7151(90)90117-Y
  7. Int. J. of KCORE v.4 no.2 Bending strength characteristic of $Al_{18}B4O_{33}W$/AC4CH composites by heat treament Yoon H.K.;Lee S.P.
  8. J. Americal Ceramic Society v.74 no.4 Modelling of Thermal Spalling during EDM of Titanium Diboride Gadalla. A.M.;Bozkurt, B.;Faulk, N.M. https://doi.org/10.1111/j.1151-2916.1991.tb06928.x
  9. Acta Metall. Mater. v.43 Deformation and fracture behavior of Nb in Nb5Si3/Nb laminates and its effect on laminate toughness Kajuch, J.;Short, J.;Lewandowski, J.J. https://doi.org/10.1016/0956-7151(94)00391-T
  10. Mater. Sci. Eng. v.A144 Poweder processing of intermetallic alloys and intermetallic matrix composite Stoloff, N.S.;Alman, D.E.
  11. Metall. Mater. Trans. v.23A Ductile-phase toughening and fatigue-crack growth in Nb-reinforcement molybdenum disiliicide intermetallic composite Venkateswaea Rao, K.T.;Soboyejo, W.O.;Ritchie, R.O.
  12. Journal of Materials Processing Technology v.87 Micro-hole machining of carbide by EDM Yan. B.H.;Huang, F.Y.;Chow, H.M.;Tsai, J.Y. https://doi.org/10.1016/S0924-0136(98)00345-8