Synthesis and Dyeing Properties of Reactive Disperse Dye Having Acetoxyethylsulfone Group

아세톡시에틸술폰계 반응성 분산염료의 합성과 염색성에 관한 연구

  • 김성동 (건국대학교 공과대학 섬유공학과) ;
  • 이영신 (건국대학교 공과대학 섬유공학과) ;
  • 이병선 (건국대학교 공과대학 섬유공학과) ;
  • 정재윤 (한양대학교 섬유고분자공학과)
  • Published : 2002.12.01

Abstract

The aim of this work is to synthesize a new type of reactive disperse dye having an acetoxyethylsulfone group which is expected to have the favorable properties of both a disperse dye and a reactive dye and to study dyeing properties of the new dyes in application to nylon and a silk fabrics. The reactive disperse dye could be synthesized by the coupling reaction of diazotized 4-hvdroxyethylsulfone aniline with N-cyanoethyl-N-ethyl aniline and subsequent acetylation of the hydroxy group with acetic anhydride. The most appropriate pH for the dyeing of nylon fabric was 7 and suitable dyeing temperature was 80-100 "C. The build-up onto nylon fiber was good and various color fastnesses were good to excellent. The most appropriate pH for the dyeing of silk fabric was found to be 9. The build-up properties onto silk fiber were good, but the fixation was not as food as in the case of nylon fiber and various color fastnesses were generally good.good.

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References

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