DOI QR코드

DOI QR Code

폐종이컵을 이용한 이온교환체 제조와 중금속제거특성

Preparation of ion exchanger from waste paper cup and removal characteristics of heavy metal

  • 발행 : 2002.09.01

초록

Waste paper cup was sulfonated to be used as ion exchanger. Removal characteristic of copper and lead ion by prepared ion exchanger was investigated. The sulfonation was conformed by the high intensity band of $SO_3H$ group around 1100~$1160cm^{-1}$. The synthesized ion exchanger had greater removal ability for copper and lead ion than the original waste paper cup. Ion exchange system reached the final equilibrium plateau within 30min. The maximum removal capacities $q_{max}$ were calculated as 9.79mg/g fur copper and 15.95mg/g for lead, respectively. The affinity of lead based on a weight was higher than that of copper. The ion exchange phenomena appeared to follow a typical Freundlich isotherm.

키워드

참고문헌

  1. 김인배, 김승호, 김병욱, 박주량, 2000, 최신폐기물, 신광문화사, 15.
  2. Davies, D. J. A. and B. G. Bennett, 1983, Exposure Commitment Assessments of Environmental Research Centre, London.
  3. Manahan, S. E., 1991, Environmental Chemistry, Lewis, Chelsea, MI, 5th ed.
  4. Murley, L., 1992, Pollution Handbook, National Society for Clean Air and Environmental Protection, Brighton.
  5. Kabata-Pendias, A. and H. Pendias, 1984, Trace Elements in Soils and Plants, CRC Press, Boca Raton.
  6. Train, R. E., 1979, Quality Criteria for Water, Castle House, London.
  7. Bowen, H. J. M., 1979, The Environmental Chemistry of the Elements, Academic Press, London.
  8. Lee, M. G. and K. H. Suh, 1996, Study on Adsorption of heavy metal ions by Cheju scoria, J. of Kor. Environ. Sci. Soc., 5(2), 195 -201.
  9. Lee, M. G., G. Yi, B. J. Ahn, and F. Roddick, 2000, Conversion of coal fly ash into zeolite and heavy metal removal characteristics of the products, Kor. Jour. of Chem. Eng., 17(3), 325-331. https://doi.org/10.1007/BF02699048
  10. Kim, M. S., W. T. Kwon, and K S. Jeon, 1987, Cation exchanger properties of synthetic zeolite A from kaolin, Hwahak Konghak, 25(6), 570-577.
  11. Kim, Y., D. S. Kim, S. B. Jang, and S. Y. Park, 1996, Studies on the removal of metal ions with domestic Pohang zeolites and synthetic zeolites, J. of KSEE, 18(5), 2-16.
  12. Altm, O., H. O. Ozbelge and T. Dogu, 1998, Use of general purpose adsorption isotherms for heavy metal-clay mineral interactions., J. Colloid and Interface Sci., 198, 130-140. https://doi.org/10.1006/jcis.1997.5246
  13. Du, Qing, Z. Sun, W. Forsling, and H. Tang, 1997, Adsorption of copper at aqueous illite surfaces, J. Colloid and Interface Sci., 187, 232-242. https://doi.org/10.1006/jcis.1996.4676
  14. Nikiforv, I. A., A. Y. Nikiforov, and V. P. Sevost'yanov, 1997, Sorption of heavy metal cations on silica clay, Russian J. Applied Chem., 70(7), 1215-1216.
  15. Jeong, E. D., H. S. Kim, K. W. Park, and U. H. Paek, 1999, A study on physical properties and adsorption characteristics of heavy metal ions of loess, J. of Kor. Environ. Sci., 8(4), 491-496.
  16. Choi, K. S. and H. S. Ahn, 1990, A study on synthesis of cross-linked chitosan phosphate and adsorption characteristics of metallic ions, Polymer, 14(5), 516-526.
  17. Park, H. J., B. H. Lee, B. H. Lee, S. U. Jeong, J. W. Jeong, and U. Jeong, 2001, Calcination characteristics of Corbicular japonica and Ostrea virginica, J. of KSEE, 23 (11), 1835-1842.
  18. 황명천, 맹기석, 1980, 톱밥이온교환체를 이용한 염산-에탄올 혼합용액에서의 양이농분포계수 및 그의 분리에 관한 연구, 충남대 공업교육연구소 논문집, 3(2), 102-106.
  19. Kim, D. W., H. Y. Song, M. C. Hwang, and H. H. Ryu, 1981, Capacity of oil cake ion exchanger, J. of Kor. Chem Soc., 25(5), 300-305.
  20. Song, H. C. and M. C. Hwang, 1981, Soybean oil cake as cation exchanger, Report Ind. Edu. Res. Center, Chungnam Nat. Univ., 4(1), 173-178.
  21. 김동원, 유화상, 1985, 탄종별 양이온교환체의 합성과 그의 이온교환용량, 대한공업교육학회지, 10(2), 143-152.
  22. Volesky, B., 1990, Biosorption of heavy metals, CRC press, 158.
  23. Kam, S. K., D. S. Kim, and M. G. Lee, 1999, Comparison of removal performance of divalent heavy metals by natural and pretreated zeolites, J. of Kor. Environ. Sci. Soc., 8(3), 399-409.