DOI QR코드

DOI QR Code

Nylon 6/Polypropylene 블렌드의 충격특성 및 모폴로지

Impact Characteristics and Morphology of Nylon 6/Polypropylene Blends

  • 김종국 (서울시립대학교 화학공학과) ;
  • 윤주호 (서울시립대학교 화학공학과) ;
  • 고재송 (기술표준원 생물환경과) ;
  • 최형기 (기술표준원 생물환경과) ;
  • 김상욱 (서울시립대학교 화학공학과)
  • Kim, Jong-Guk (Dept.of Chemical Engineering, University of Seoul) ;
  • Yun, Ju-Ho (Dept.of Chemical Engineering, University of Seoul) ;
  • Go, Jae-Song (Biotechnolog & Environmental Eng, Div., Agency for Technology and Standards, MOCIE) ;
  • Choe, Hyeong-Gi (Biotechnolog & Environmental Eng, Div., Agency for Technology and Standards, MOCIE) ;
  • Kim, Sang-Uk (Dept.of Chemical Engineering, University of Seoul)
  • 발행 : 2002.01.01

초록

Melt blends of maleic anhydride grafted polypropylerle(PP-g-MA) and Nylon 6 were prepared to study the influence of chemical reaction between the two polymer components. By adding the MA grafted polystyrene pold (ethylene/butadiene) and polystyrene[SEBS-g-MA] as the compatible modifiers to reinforce the impact resistance, the Izod impact strength, high rate impact strength and morphology were studied. The notched Izod impact strength increased with the content of PP-g-MA and SEBS- g-MA. The energy of high rate impact strength increased as the thickness of specimen increased, while, it increased as the specimen displacement decreased. In the morphology observed by SEM, finally, we confirmed the improvement of the compatibilization and interfacial adhesion with the content of SEBS-g-MA. The continuous phase of PP-g-MA was the main cause of the modified properties.

키워드

참고문헌

  1. F. Ide and A. Hasegawa, J. Appl. Polym. Sci., 18,963 (1974) https://doi.org/10.1002/app.1974.070180402
  2. S.J. Park, B.K. Ki and H.M. Jeong, Eur. Polym. J., 26, 131 (1990) https://doi.org/10.1016/0014-3057(90)90176-5
  3. T. Nishio, Y. Suzuki, K. Kojima and M. Kakugo, 7th Annual Meeting Polymer Processing Society, Hamilton, Ontario, Canada, (1991)
  4. T. Nishio, Y. Suzuki, K. Kojima and M. kakugo, J. Polym. Eng. (Japan),10, 123 (1991)
  5. S. Hosoda, K. Kojima, Y. Kanda and M. Aoyagi, Polym. Networks Blends, 1, 51 (1991)
  6. R. Holsti-Miettinen and J. Seppala, Polym. Eng. Sci., 32, 868 (1992) https://doi.org/10.1002/pen.760321306
  7. F.P. La Mantia, Adv. Polym. Tech., 12, 47 (1993) https://doi.org/10.1002/adv.1993.060120105
  8. P. Scholz, D. Froelich and R. Muller, J. Rheology, 33, 481 (1989) https://doi.org/10.1122/1.550024
  9. B. Ohlsson, H. Hassander and B. Tornell, Polymer. 26, 6705 (1998) https://doi.org/10.1016/S0032-3861(97)10290-7
  10. J.H. Kim, H.I. Kim, H.Y. Song, H.C. Kim and K.Y. Lee, Polymer(Korea). 20, 791 (1996)
  11. F.P. Tseng, J.J. Lin, C.R. Tseng and F.C. Chang, Polymer. 42, 713 (2001) https://doi.org/10.1016/S0032-3861(00)00400-6
  12. ASTM D 3763-95a
  13. S. George, R. Joseph, and S. Thomas, Polymer. 36, 4405 (1995) https://doi.org/10.1016/0032-3861(95)96846-Z