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Effect of Si, Mo, and Mn on the Corrosion Characteristics of Zr-0.2Sn-0.8Nb Alloy

Zr-0.2Sn-0.8Nb 합금의 부식특성에 대한 Si, Mo 및 Mn 원소의 첨가영향

  • Lee, Myeong-Ho ( Advanced Zr Alloy Development, Korea Atomic Energy Research Institute) ;
  • Choe, Byeong-Gwon ( Advanced Zr Alloy Development, Korea Atomic Energy Research Institute) ;
  • Jeong, Yong-Hwan ( Advanced Zr Alloy Development, Korea Atomic Energy Research Institute)
  • 이명호 (한국원자력연구소 지르코늄 신합금핵연료피복관개발팀) ;
  • 최병권 (한국원자력연구소 지르코늄 신합금핵연료피복관개발팀) ;
  • 정용환 (한국원자력연구소 지르코늄 신합금핵연료피복관개발팀)
  • Published : 2002.03.01

Abstract

The Zr-0.2Sn-0.8Nb-X(X = 0~200ppm Si, 0~0.4wt.% Mo and Mn respectively) ingots for test specimens were manufactured by a vacuum arc re-melting method to find out the effect of Si, Mo, and Mn on the corrosion characteristics of the Zr-0.2Sn-0.8Nb alloy. After being heat-treated and rolled repeatedly out to be flat materials, they were finally heat-treated at 51$0^{\circ}C$ for three hours and used as the specimens for corrosion tests. The corrosion behavior of the specimens was studied in both 40$0^{\circ}C$ steam for 200 days and in aqueous 70 ppm LiOH solution at 36$0^{\circ}C$ for 90 days. From the study it was found that Si from 80 to 200 ppm contributed to increasing the corrosion resistance of Zr-0.2Sn-0.8Nb alloy in both steam and LiOH solution. This study also showed that Mn from 0.1 to 0.4% caused to go up the corrosion resistance, whereas Mo played a apart in improving the corrosion resistance only between 0.05 and 0.2 wt.%.

Keywords

References

  1. R.J. Comstock, G. Schoenberger and G.P. Sabol, ASTM STP 1295, 710-725 (1996)
  2. J.P. Mardon, D. Charquet and L. Senevat, ASTM 1354, 505-524 (2000)
  3. J.T. Willse, G.L. Garner, Proceedings of the 2000 ANS International Topical Meeting on LWR Fuel Performance, Park City, Utah, April 10-13, 1-4-1 (2000)
  4. K. Goto, S. Matsumoto, T. Murata, T. Miyashita, H. Anada, H. Abe, Proceedings of 2000 ANS International Topical Meeting on LWR Fuel Performance, Park city, Utah, April 10-13, 1-8-1 (2000)
  5. Yasuhiro Irisa, Sigemitsu Suzuki, Kenji Murai, R. Sabate, Ken Goto, J.M. Alonso, Proceedings of 2000 ANS International Topical Meeting on LWR Fuel Performance, Park city, Utah, April 10-13, 1-7-1 (2000)
  6. Ambattsumyan. R.S. et al., Proceedings of the Second International Conference on the Peaceful Uses of Atomic Energy, Geneva, Vol. 5., 2044 (1958)
  7. S. Kass, J.D. Grozier and F.L. Shubert, Effect of Silicon, Nitrogen and Oxygen on the Corrosion and Hydriding Absorption of Zircaloy-2, Corrosion. Vol. 20, 350 (1964) and U.S. Report WAPDD-283, Nov. (1963) https://doi.org/10.5006/0010-9312-20.11.350t
  8. S. Kass, J.D. Grozier and F.L. Shubert, Effect of Silicon, Nitrogen and Oxygen on the Corrosion and Hydriding Absorption of Zircaloy-2 and U.S. Report WAPDD-283, Nov. (1963)
  9. Garzarolli, F., Schumann, R. et al, ASTM STP 1245, 709-723 (1994)
  10. Y.B. Chun, S.K. Hwang, M.H. Kim, S.I. Kwun, Y.S. Kim, JNM 265, 28-37 (1999) https://doi.org/10.1016/S0022-3115(98)00651-5
  11. J.H. Lee, S.K. Hwang, M.H. Kim and S.I. Kwun, J. Kor. Inst. Met. & Mater. Vol. 38(6), 745 (2000)
  12. Ivanov, O.S. and V.K. Grigorovich, Proceedings of the Second International Conference on the Peaceful Uses of Atomic Energy. Geneva., Vol. 5, 2046 (1958)
  13. B.G. Parfenov, V.V. Gerasimov, and G.I. Venediktova, Corrosion of Zirconium and Zirconium Alloys. A Symposium Presented at the Winter Meeting. Nov 20, 13 (1963)
  14. Derek O. Northwood and Daniel T. Lim: Canadian Metallurgical Quarterly, Vol. 18, 441-467 (1979) https://doi.org/10.1179/cmq.1979.18.4.441
  15. Bibb, A.E. et al, KAPL-M-AEB-8, (1960)
  16. Rubenstein, L.S. et al., US Pat.3097094, Class 77-17, 6 Sept. (1960)
  17. J.N. Wanklyn, Report UK AERE-R3768, Part II, (1961)
  18. Isobe, T. and Matusuo. et al, ASTM STP 1132, 346-367 (1991)
  19. Ramasubramanian, N., Balakrishnan, P.V.: ASTM STP 1245, 378 (1994)
  20. Ramasubramanian, N., Precoanin, N., Ling, V.C.: ASTM STP 1023, 187 (1989)
  21. Ramasubramanian, N., ASTM STP 1132, 613 (1991)
  22. Ding, Y., Northwood, D.O., J. Nucl. Mater. 202, 180-192 (1993) doi:10.1016/0022-3115(93)90041-V
  23. J. Godlewski: ASTM 1245, 663 (1994)
  24. H.C. Kim, M.H. Lee, S.Y. Park and Y.H. Jeong: J. Kor. Inst. Met. & Mater. Vol. 37(12), 1527 (1999)
  25. B. Lustman and F. Kerze, Jr., The Metallugy of Zirconium, 1st Edition, Mcgraw-hill book company, inc., 463-471 (1955)