Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Study for the Preparation of Deodorizing Fiber ( II ) - Preparations of Deodorizing Fibers using Metal-Phthalocyanines -

소취 섬유의 제조에 관한 연구 (II) - 금속 프탈로시아닌을 이용한 소취 섬유의 제조 -

  • Published : 2002.02.01
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Abstract

The preparations of deodorizing fibers using medal-phthalocyanines have been investigated. The five metal-phthalocyanine derivatives(M-taPc, M=Fe, Co, Ni, Zn, Cu) were prepared in modest to good yields. The metal-phthalocyanine derivative as a deodorant material was introduced to fibers by a dyeing method. The deodorant activity(D.A.) of these deodorizing fibers was measured by chromogenic gas detector tubes. In comparison with untreated fibers, these deodorizing fibers was remarkably effective against $NH_3$ and CH3SH. More than 99% of ammonia can be removed within 20 min. The D.A.(%) of fiber adsorbed M-taPc was more than 80% after 90min.

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References

  1. J. Text. Mac. Soc. Japan v.42 no.9 香りの纖維 えすぷりどふれる A. One https://doi.org/10.4188/transjtmsj.42.9_P440
  2. J. Text. Mac. Soc. Japan. v.40 no.3 消臭制とるの評價法 Y. Shigeta https://doi.org/10.4188/transjtmsj.40.3_P104
  3. Functional Fiber Y. Washino
  4. Makromol. Chem. v.181 Functional Metalporphyrazine derivatives and their polymers, 3 H. Shirai;A. Maruyama;J. Takano;K. Kobayashi;N. Hojo https://doi.org/10.1002/macp.1980.021810304
  5. Makromol. Chem. v.181 Functional Metal-porphyrazine derivatives and their polymers, 5 H. Shirai;A. Maruyama;M. Konishi;N. Hojo https://doi.org/10.1002/macp.1980.021810504
  6. J. Am. Chem. Soc. v.97 Porous, polymer-bonded metalloporphyrins L. D. Rollmann https://doi.org/10.1021/ja00841a023
  7. J. Polym. Sci., Polym. Lett. Ed. v.17 Synthesis and catalaselike activity of polystyrene-bonded Fe(Ⅲ)-phthalocyanine H. Shirai;A. Maruyama;K. Kobayashi;N. Hojo;K. Urushido https://doi.org/10.1002/pol.1979.130171007
  8. Makromol. Chem. v.181 Functional Metalporphyrazie derivatives and their polymers, 4 H. Shirai;A. Maruyama;K. Kobayashi;N. Hojo;K. Urushido https://doi.org/10.1002/macp.1980.021810305
  9. J. Polym. Sci., Polym. Lett. Ed. v.21 Synthesis and catalaselike activity of Fe(Ⅲ)-phthalocyanine covalently bonded on poly(2-vinylpyridine-co-styrene) H. Shirai;S. Higaki;K. Hanabusa;N. Hojo https://doi.org/10.1002/pol.1983.130210301
  10. J. Text. Mac. Soc. Japan. v.40 no.3 酵素料似機能による消臭纖維 H. Shirai https://doi.org/10.4188/transjtmsj.40.3_P125
  11. Makromol. Chem. v.178 Functional Metal-porphyrazine derivatives and their polymers, 1 H. Shirai;S. Yagi;A. Suzuki;N. Hojo https://doi.org/10.1002/macp.1977.021780703
  12. J. Text. Mac. Soc. Japan. v.40 no.3 消臭纖維 「でおめなひい？簾？ Y. Komatsu https://doi.org/10.4188/transjtmsj.40.3_P141