The Effect of Small Additions of Zr, Cr, Mg, Al, and Si on the Oxidation of 6:4 Brass

  • 이동복 (플라즈마 응용 표면기술 연구 센터) ;
  • 문재진 (플라즈마 응용 표면기술 연구센터)
  • 발행 : 1999.06.01

초록

The oxidation behavior of 60%Cu-40%Zn brass haying small amounts of Zr, Cr, Mg, Al, and Si was studied between 873 and 1043 K in air. The alloying element of Mg was harmful, while other alloying elements were beneficial to oxidation resistance. Particularly, the simultaneous addition of Al and Si decreased the oxidation rate drastically. During oxidation, Zr formed ZrO₂, Cr formed CuCr₂O₄, Mg formed MgO, Al formed A1₂CuO₄, and Si formed amorphous SiO₂. These oxides were incorporated in the oxide scale composed predominantly of ZnO. The oxide scales formed on all the tested alloyswere prone to cracking, wrinkling, and spallation.

키워드

참고문헌

  1. Physical Metallurgy Principles(3rd ed.) R.E.Reed-Hill;R.Abbaschian
  2. Br. Corros. J. v.3 D.P.Whittle;G.C.Wood
  3. Oxid. Met. v.2 G.C.Wood
  4. Oxid. Met. v.2 B.Chattopadhyay;G.C.Wood
  5. J. Inst. Met. v.46 J.S.Dunn
  6. Corros. Sci. v.5 C.Wagner
  7. Corrosion v.21 R.A.Rapp
  8. Proc. of Int. Symp. on High-Temperature Corrosion and Protection 2000 D.B.Lee;S.H.Kim;S.B.Jung
  9. Mater. Sci. Forum v.43 H.Nagai
  10. Oxid. Met. v.8 J.D.Kuenzly;D.L.Douglass
  11. Surf. Interface Anal. v.12 P.A.van Manen;E.W.A.Young;D.Schalkoard;C.J.van der Wekken;J.H.W. de Wit
  12. Oxidation of High-Temperature Intermetallics J.L.Smialek;J.Doychak;D.J.Gaydosh;T.Grobstein(ed.);J.Doychack(ed.)
  13. Thermochemical Data of Pure Substances I.Barin
  14. Oxidation of Metals and Alloys D.L.Douglass
  15. Mater. Sci. Tech. v.5 F.H.Stott