Microstructure and Electrical Properties of Low Temperature Processed Ohmic Contacts to p-Type GaN

  • Park, Mi-Ran (Basic Research Laboratory, ETRI) ;
  • Song, Young-Joo (Basic Research Laboratory, ETRI) ;
  • Anderson, Wayne A. (Department of Electrical Engineering, State University of New York)
  • Received : 2002.01.23
  • Published : 2002.10.31

Abstract

With Ni/Au and Pd/Au metal schemes and low temperature processing, we formed low resistance stable Ohmic contacts to p-type GaN. Our investigation was preceded by conventional cleaning, followed by treatment in boiling $HNO_3$:HCl (1:3). Metallization was by thermally evaporating 30 nm Ni/15 nm Au or 25 nm Pd/15 nm Au. After heat treatment in $O_2$ + $N_2$ at various temperatures, the contacts were subsequently cooled in liquid nitrogen. Cryogenic cooling following heat treatment at $600^{\circ}C$ decreased the specific contact resistance from $9.84{\times}10^{-4}$ ${\Omega}cm^2$ to $2.65{\times}10^{-4}$ ${\Omega}cm^2$ for the Ni/Au contacts, while this increased it from $1.80{\times}10^{-4}$ ${\Omega}cm^2$ to $3.34{\times}10^{-4}$ ${\Omega}cm^2$ for the Pd/Au contacts. The Ni/Au contacts showed slightly higher specific contact resistance than the Pd/Au contacts, although they were more stable than the Pd contacts. X-ray photoelectron spectroscopy depth profiling showed the Ni contacts to be NiO followed by Au at the interface for the Ni/Au contacts, whereas the Pd/Au contacts exhibited a Pd:Au solid solution. The contacts quenched in liquid nitrogen following sintering were much more uniform under atomic force microscopy examination and gave a 3 times lower contact resistance with the Ni/Au design. Current-voltage-temperature analysis revealed that conduction was predominantly by thermionic field emission.

Keywords

References

  1. Jpn. J. Appl. Phys. v.34 High-Brightness InGaN Blue, Green and Yellow Light-Emitting Diodes with Quantum Well Structures Nakamura, S.;Senoh, M.;Iwasa, N.;Nagahama, S.
  2. Jpn. J. Appl. Phys. v.34 Superbright Green InGaN Single-Quantum-Well-Structure Light-Emitting Diodes Nakamura, S.;Senoh, M.;Iwasa, N.;Nagahama, S.;Yamada, T.;Mukai, T.
  3. Jpn. J. Appl. Phys. v.30 High-Power GaN P-N Junction Blue-Light-Emitting Diodes Nakamura, S.;Senoh, M.
  4. Jpn. J. Appl. Phys. v.35 InGaN Multi-Quantum-Well-Structure Laser Diodes with Cleaved Mirror Cavity Facets Nakamura, S.;Senoh, M.;Nagahama, S.;Iwasa, N.;Yamada, T.;Matsushita, T.;Kiyoku, H.;Sugimoto, Y.
  5. Appl. Sur. Sci. v.117;118 Interfacial Reactions in The Formation of Ohmic Contacts to Wide Bandgap Semiconductor Holloway, P.H.;Kim, T.J.;Trexler, J.T.;Miller, S.;Fijol, J.J.;Lampert, W.V.;Haas, T.W.
  6. J. Elec. Mat. v.28 Effects of Annealing in An Oxygen Ambient on Electrical Properties of Ohmic Contacts to p-Type GaN Koide, Y.;Maeda, T.;Kawakami, T.;Fujita, S.;Uemura, T.;Shibata, N.;Murakami, M.
  7. Mat. Res. Soc. Symp. Proc. v.449 Comparison of Ni/Au, Pd/Au, and Cr/Au Metallizations for Ohmic Contacts to p-GaN Trexler, J.T.;Pearton, S.J.;Holloway, P.H.;Mier, M.G.;Evans, K.R.;Karlicek, R.F
  8. Mat. Res. Soc. Symp. Proc. v.468 Low Resistance Contacts to p-Type GaN Kim, T.;Khim, J.;Chae, S.;Kim, T.
  9. Solid-State Electronics v.45 no.5 Low-Resistance Ni/Au Ohmic Contact to Mg-Doped of $A_{10.15}Ga_{0.85}N/GaN$ Superlattices Kuo, C.H.;Sheu, J.K.;Chi, G.C.;Huang, Y.L.;Yeh, T.W.
  10. J. Vacuum Sci. & Tech. B v.19 no.3 Electrical Properties of Pd-Based Ohmic Contact to p-GaN Kim, D.W.;Bae, J.C.;Kim, W.J.;Baik, H.K.;Lee, S.M.
  11. Appl. Phy. Lett. v.73 Low Resistance Pd/Au Ohmic Contacts to p-Type GaN Using Surface Treatment Kim, J.K.;Lee, J.
  12. Metal-Semiconductor Contacts Rhoderick, E.H.;Williams, R.H.
  13. Mat. Res. Soc. Symp. Proc. v.468 Phase Formation and Morphology in Nickel and Nickel/Gold Contacts to Gallium Nitride Venugopalan, H.S.;Mohney, S.E.;Luther, B.P.;Delucca, J.M.;Walter, S.D.;Redwing, J.M.;Bulman, G.E.
  14. Mat. Res. Soc. Symp. Proc. v.395 Interfacial Reactions Between Metal Thin Films and p-GaN Trexler, J.T.;Miller, S.J.;Holloway, p.H.;Khan, M.A.
  15. Smithells Metals Reference Book Brandes, E.A.
  16. Mat. Res. Soc. Symp. Proc. v.449 Thermal Stability of Pt and Ni on GaN Duxstad, K.J.;Haller, E.E.;Yu, K.M.;Hirsch, M.T.;Imler, W.R.;Steigerwald, D.A.;ponce, F.A.;Romano, L.T.