동축 층류 확산화염에서의 그을음 생성

Soot Generation in a Coaxial Laminar Diffusion Flame

Soot generation by combustion process has been investigated with objective of understanding of chemical reaction responsible for its formation in a coaxial laminar propane jet diffusion flame. For the direct photos, as the coflowing air flow rate is reduced, the area of soot luminous zone increases at first, then becomes smaller and smaller, and even disappears. The aspects of soot deposition can be acquired by using nine $15{\mu}m$ thin SiC fibers are positioned horizontally across the flame. Deposited soots on SiC fibers show the soot inception point and growth and soot oxidation zone in a typical propane diffusion. Soot is not generated anymore in a oxidizer deficient conditions of near-extinction and flame is fully occupied by transparent blue flame. It suggests that nonsooting pyroligneous blue reaction is being dominant in a oxidizer deficient ambience. In comparison with luminosities of SiC fibers and flame itself, indirect evidence is found that the process of soot nucleation and growth is endothermic reaction. It is remarkable that there exists two adjacent regions to have antithesis characteristics; one is exothermic reaction of blue flame and another endothermic reaction zone of soot formation.