DOI QR코드

DOI QR Code

Electrochemical Properties of Cross-linked Polyurethane Acrylate-Based Gel Polymer Electrolyte

  • 발행 : 2002.11.01

초록

In this study, a gel polymer electrolyte was prepared from urethane acrylate and its electrochemical performances were evaluated. And, $LiCoO_2/GPE/graphite$ cells were prepared and their performances depending on discharge currents and temperatures were evaluated. The precursor containing $5 vol\%$ curable mixture had a low viscosity relatively. Ionic conductivity of the gel polymer electrolyte at room temperature and $-20^{\circ}C$ was ca. $5.9\times10^{-3}S{\cdot}cm^{-1}\;and\;1.7\times10^{-3}S{\cdot}cm^{-1}$, respectively. GPE showed electrochemical stability up to potential of 4.5V vs. $Li/Li^+.LiCoO_2/GPE/graphite$ cell showed a good high-rate and a low-temperature performance.

키워드

참고문헌

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피인용 문헌

  1. Preparation of lithium-ion polymer battery using LiNi1/3Co1/3Mn1/3O2 as a cathode material and its electrochemical properties vol.17, pp.2-4, 2006, https://doi.org/10.1007/s10832-006-9012-3
  2. Synthesis and electrochemical performances of di(trimethylolpropane) tetraacrylate-based gel polymer electrolyte vol.146, pp.1-2, 2005, https://doi.org/10.1016/j.jpowsour.2005.03.148
  3. Electrochemical performances of lithium-ion polymer battery using LiNi1/3Co1/3Mn1/3O2 as cathode materials vol.159, pp.1, 2006, https://doi.org/10.1016/j.jpowsour.2006.04.084