Journal of Applied Biological Chemistry

  • 제44권1호
  • /
  • Pages.20-22
  • /
  • 2001
  • /
  • 1976-0442(pISSN)
  • /
  • 2234-7941(eISSN)
한국응용생명화학회 (The Korean Society for Applied Biological Chemistry)
권호 표지

Regioselective Benzylic Thioether Formation from Polybydroxy Stilbene

  • Koh, Dongsoo (Department of Applied Chemistry, Dongduk Women's University) ;
  • Park, Jongmin (Department of Applied Biology and Chemistry, Konkuk University) ;
  • Lim, Yoongho (Department of Applied Biology and Chemistry, Konkuk University)
  • 투고 : 2000.11.11
  • 발행 : 2001.03.31
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초록

We have attempted to synthesize polyhydroxy stilbene compounds through the benzyl thioether moiety. During synthesis, we unexpectedly observed that demethylation of the compound under $AlCl_3$ in ethanethiol resulted in a regioselective addition of thiol to the double bond as well as complete demethylation. We report on the regioselective short synthesis for general structure and its structural identification.

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